Electrochimica Acta, volume 57, pages 14-19
Single-ion polymer electrolytes based on a delocalized polyanion for lithium batteries
1
Laboratoire de Réactivité et Chimie des Solides UMR 6007, Université de Picardie Jules Verne, 33 rue Saint-Leu, 80039 Amiens, France
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2
Plate-forme de Microscopie Électronique, Université de Picardie Jules Verne, 33 rue Saint Leu, 80039 Amiens, France
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Publication type: Journal Article
Publication date: 2011-12-01
General Chemical Engineering
Electrochemistry
Abstract
Lithium poly(4-styrenesulfonyl(trifluoromethylsulfonyl)imide) (PSTFSI) polyelectrolytes made up of SO 2 N − SO 2 CF 3 anionic groups associated with a lithium cation and attached to a polystyrene chain have been prepared. In these polymers the transference number of the lithium cation is expected to be unity while the ionic conductivity is kept high. Two different single-ion polymers with a similar final structure were synthesized by two ways, monomer free radical polymerization and polymer modification (PSTFSI (a) and PSTFSI (b), respectively). These polyelectrolytes were mixed with poly(ethylene oxide) PEO into a composite membrane to form solid electrolytes for lithium batteries. These polymer alloys were studied by scanning electron microscopy (SEM), thermal analysis and impedance spectroscopy to measure the ionic transport properties. Interestingly, ionic conductivity is about ten times higher for a membrane with PSTFSI (a) (≈10 −5 S cm −1 ) compared to a membrane with lithium poly(styrene sulfonate) or with PSTFSI (b) above PEO melting temperature.
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Citations by publishers
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IOP Publishing
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Korean Society of Industrial Engineering Chemistry
1 publication, 0.33%
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Universidad De Antioquia
1 publication, 0.33%
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1 publication, 0.33%
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IEEE
1 publication, 0.33%
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American Association for the Advancement of Science (AAAS)
1 publication, 0.33%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Meziane R. et al. Single-ion polymer electrolytes based on a delocalized polyanion for lithium batteries // Electrochimica Acta. 2011. Vol. 57. pp. 14-19.
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Meziane R., Bonnet J., Courty M., Djellab K., Armand M. Single-ion polymer electrolytes based on a delocalized polyanion for lithium batteries // Electrochimica Acta. 2011. Vol. 57. pp. 14-19.
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TY - JOUR
DO - 10.1016/j.electacta.2011.03.074
UR - https://doi.org/10.1016/j.electacta.2011.03.074
TI - Single-ion polymer electrolytes based on a delocalized polyanion for lithium batteries
T2 - Electrochimica Acta
AU - Meziane, Rachid
AU - Bonnet, Jean‐Pierre
AU - Courty, Matthieu
AU - Djellab, Karim
AU - Armand, Michel
PY - 2011
DA - 2011/12/01 00:00:00
PB - Elsevier
SP - 14-19
VL - 57
SN - 0013-4686
ER -
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@article{2011_Meziane,
author = {Rachid Meziane and Jean‐Pierre Bonnet and Matthieu Courty and Karim Djellab and Michel Armand},
title = {Single-ion polymer electrolytes based on a delocalized polyanion for lithium batteries},
journal = {Electrochimica Acta},
year = {2011},
volume = {57},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.electacta.2011.03.074},
pages = {14--19},
doi = {10.1016/j.electacta.2011.03.074}
}