Electrochimica Acta, volume 93, pages 254-263
Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions
Shaowei Feng
1
,
Dongyang Shi
1
,
Fang Liu
1
,
Liping Zheng
1
,
Jin Nie
1
,
Wengfang Feng
1
,
Xuejie Huang
2
,
Michel Armand
3
,
Zhibin Zhou
1
2
3
CIC Energigune, Alava Technology Park, Albert Einstein, 4801510 MIÑANO Álava, Spain
|
Publication type: Journal Article
Publication date: 2013-03-01
General Chemical Engineering
Electrochemistry
Abstract
New single lithium-ion conducting polymer electrolytes are prepared by a copolymerization of the two monomers, lithium (4-styrenesulfonyl)(trifluoromethanesulfonyl)imide (LiSTFSI) and methoxy-polyethylene glycol acrylate (MPEGA, CH2=HCO2-(CH2CH2O)(n)-CH3, n=8) in various monomer ratios. The structures and compositions of the prepared lithium poly[(4-styrenesulfonyl) (trifluoromethanesulfonyl)imide-co-methoxy-polyethylene glycol acrylate] (Li[PSTFSI-co-MPEGA]) copolymers are characterized by H-1 and F-19 NMR, and gel permeation chromatography (GPC). For comparison, the corresponding blended polymer electrolytes comprising lithium poly[(4-styrenesulfonyl) (trifluoromethanesulfonyl)imide] (LiPSTFSI) and poly(ethylene oxide) (PEO) are also prepared and characterized. The fundamental properties of these two types of lithium-ion conducting polymer electrolytes are comparatively studied, in terms of phase transitions, thermal stability, XRD, ionic conductivities, lithium-ion transference numbers (t(Li)(+)), and electrochemical stabilities. Both types of the polymer electrolytes are thermally stable up to 300 degrees C. While both types of polymer electrolytes exhibit single lithium-ion conducting behavior with t(Li)(+)>0.9, the solid-state ionic conductivities of the Li[PSTFSI-co-MPEGA] copolymer electrolytes are all higher by 1-3 orders in magnitude than those of the blended ones, irrespective of the concentration of lithium ions. The highest ionic conductivities for the copolymer electrolytes are 7.6 x 10(-6) S cm(-1) at 25 degrees C and reach 10(-4) S cm(-1) at 60 degrees C, which are obtained at the ethylene oxide (EO) unit/Li+ ratio of 20.5. (C) 2013 Elsevier Ltd. All rights reserved.
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Feng S. et al. Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions // Electrochimica Acta. 2013. Vol. 93. pp. 254-263.
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Feng S., Shi D., Liu F., Zheng L., Nie J., Feng W., Huang X., Armand M., Zhou Z. Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions // Electrochimica Acta. 2013. Vol. 93. pp. 254-263.
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TY - JOUR
DO - 10.1016/j.electacta.2013.01.119
UR - https://doi.org/10.1016/j.electacta.2013.01.119
TI - Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions
T2 - Electrochimica Acta
AU - Feng, Shaowei
AU - Shi, Dongyang
AU - Liu, Fang
AU - Zheng, Liping
AU - Nie, Jin
AU - Feng, Wengfang
AU - Huang, Xuejie
AU - Armand, Michel
AU - Zhou, Zhibin
PY - 2013
DA - 2013/03/01 00:00:00
PB - Elsevier
SP - 254-263
VL - 93
SN - 0013-4686
ER -
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@article{2013_Feng,
author = {Shaowei Feng and Dongyang Shi and Fang Liu and Liping Zheng and Jin Nie and Wengfang Feng and Xuejie Huang and Michel Armand and Zhibin Zhou},
title = {Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions},
journal = {Electrochimica Acta},
year = {2013},
volume = {93},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.electacta.2013.01.119},
pages = {254--263},
doi = {10.1016/j.electacta.2013.01.119}
}