Electrochimica Acta, volume 180, pages 37-42

W-Doped Li7La3Zr2O12 Ceramic Electrolytes for Solid State Li-ion Batteries

Yiqiu Li ¹

Zheng Wang ¹

Cao Yang ¹

Fuming Du ¹

Cheng Chen ¹

Zhonghui Cui ¹

X. Guo ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Ding-xi Road, Shanghai 200050 (China). |

Publication type: Journal Article

Publication date: 2015-10-01

Elsevier

Journal: Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor: 6.6

ISSN: 00134686

DOI: 10.1016/j.electacta.2015.08.046

Copy DOI

General Chemical Engineering

Electrochemistry

Abstract

W-doped Li 7 La 3 Zr 2 O 12 electrolytes with composition of Li 7-2x La 3 Zr 2-x W x O 12 (LLZWO, x = 0-0.55) were prepared by conventional solid state reaction. The incorporation of W proves beneficial to stabilization of cubic phase and densification of the ceramic, resulting in relative density of 96% and ionic conductivity of 6.6 × 10 −4 S cm −1 at 25 °C. Further analysis indicates that the LLZWO is not only chemically but also electrochemically (at least up to 4.5 V) stable against Li metal anodes. The batteries consisting of Li/LLZWO/Electrolyte-soaked separator/LiNi 0.33 Mn 0.33 Co 0.33 O 2 at 25 °C exhibit the capacity of 142 mAh g −1 at a constant current of 15 mA g −1 at the first discharge, which could run for 20 cycles with capacity retention of 94%. These results indicate that the W-doped LLZO ceramics are promising electrolytes for solid state lithium ion batteries.

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Current Nanoscience	Current Nanoscience, 1, 0.66% Current Nanoscience 1 publication, 0.66%
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Functional Materials Letters	Functional Materials Letters, 1, 0.66% Functional Materials Letters 1 publication, 0.66%
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Citations by publishers

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Elsevier	Elsevier, 65, 43.05% Elsevier 65 publications, 43.05%
American Chemical Society (ACS)	American Chemical Society (ACS), 19, 12.58% American Chemical Society (ACS) 19 publications, 12.58%
Wiley	Wiley, 14, 9.27% Wiley 14 publications, 9.27%
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American Institute of Physics (AIP)	American Institute of Physics (AIP), 2, 1.32% American Institute of Physics (AIP) 2 publications, 1.32%
American Physical Society (APS)	American Physical Society (APS), 1, 0.66% American Physical Society (APS) 1 publication, 0.66%
ASME	ASME, 1, 0.66% ASME 1 publication, 0.66%
Bentham Science	Bentham Science, 1, 0.66% Bentham Science 1 publication, 0.66%
World Scientific	World Scientific, 1, 0.66% World Scientific 1 publication, 0.66%
Thomas Telford	Thomas Telford, 1, 0.66% Thomas Telford 1 publication, 0.66%
Tsinghua University Press	Tsinghua University Press, 1, 0.66% Tsinghua University Press 1 publication, 0.66%
University of Science and Technology Beijing	University of Science and Technology Beijing, 1, 0.66% University of Science and Technology Beijing 1 publication, 0.66%
IOP Publishing	IOP Publishing, 1, 0.66% IOP Publishing 1 publication, 0.66%
Chinese Ceramic Society	Chinese Ceramic Society, 1, 0.66% Chinese Ceramic Society 1 publication, 0.66%
Walter de Gruyter	Walter de Gruyter, 1, 0.66% Walter de Gruyter 1 publication, 0.66%
Chinese Physical Society	Chinese Physical Society, 1, 0.66% Chinese Physical Society 1 publication, 0.66%
Institute of Research and Community Services Diponegoro University (LPPM UNDIP)	Institute of Research and Community Services Diponegoro University (LPPM UNDIP), 1, 0.66% Institute of Research and Community Services Diponegoro University (LPPM UNDIP) 1 publication, 0.66%
Universidade Federal de Sao Carlos	Universidade Federal de Sao Carlos, 1, 0.66% Universidade Federal de Sao Carlos 1 publication, 0.66%
Hindawi Limited	Hindawi Limited, 1, 0.66% Hindawi Limited 1 publication, 0.66%
Korean Ceramic Society	Korean Ceramic Society, 1, 0.66% Korean Ceramic Society 1 publication, 0.66%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 0.66% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 0.66%
	10 20 30 40 50 60 70

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Li Y. et al. W-Doped Li7La3Zr2O12 Ceramic Electrolytes for Solid State Li-ion Batteries // Electrochimica Acta. 2015. Vol. 180. pp. 37-42.

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Li Y., Wang Z., Yang C., Du F., Chen C., Cui Z., Guo X. W-Doped Li7La3Zr2O12 Ceramic Electrolytes for Solid State Li-ion Batteries // Electrochimica Acta. 2015. Vol. 180. pp. 37-42.

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TY - JOUR

DO - 10.1016/j.electacta.2015.08.046

UR - https://linkinghub.elsevier.com/retrieve/pii/S0013468615302978

TI - W-Doped Li7La3Zr2O12 Ceramic Electrolytes for Solid State Li-ion Batteries

T2 - Electrochimica Acta

AU - Li, Yiqiu

AU - Wang, Zheng

AU - Yang, Cao

AU - Du, Fuming

AU - Chen, Cheng

AU - Cui, Zhonghui

AU - Guo, X.

PY - 2015

DA - 2015/10/01 00:00:00

PB - Elsevier

SP - 37-42

VL - 180

SN - 0013-4686

ER -

BibTex

Cite this

BibTex Copy

@article{2015_Li,

author = {Yiqiu Li and Zheng Wang and Cao Yang and Fuming Du and Cheng Chen and Zhonghui Cui and X. Guo},

title = {W-Doped Li7La3Zr2O12 Ceramic Electrolytes for Solid State Li-ion Batteries},

journal = {Electrochimica Acta},

year = {2015},

volume = {180},

publisher = {Elsevier},

month = {oct},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0013468615302978},

pages = {37--42},

doi = {10.1016/j.electacta.2015.08.046}

}

Found error?

Publisher

Elsevier

Journal

Electrochimica Acta

Quartile SCImago

Quartile WOS

Impact factor

6.6

ISSN

00134686 (Print)