Elsevier
Electrochimica Acta
,  том 184 ,  страницы 323-330

Nitrate and Nitrite Electrocatalytic Reduction at Layer-by-Layer Films Composed of Dawson-type Heteropolyanions Mono-substituted with Transitional Metal Ions and Silver Nanoparticles

Тип публикации: Journal Article
Дата публикации: 2015-12-01
Elsevier
scimago Q1
wos Q1
БС1
SJR: 1.106
CiteScore: 10.6
Impact factor: 5.6
ISSN: 00134686, 18733859
General Chemical Engineering
Electrochemistry
Краткое описание
A series of Dawson-type heteropolyanions (HPAs) mono-substituted with transitional metal ions ( α2 -[P 2 W 17 O 61 Fe III ] 8− , α2 -[P 2 W 17 O 61 Cu II ] 8− and α2 -[P 2 W 17 O 61 Ni II ] 8− ) have exhibited electrocatalytic properties towards nitrate and nitrite reduction in slightly acidic media (pH 4.5). The immobilization of these HPAs into water-processable films developed via layer-by layer assembly with polymer-stabilized silver nanoparticles led to the fabrication of the electrocatalytic interfaces for both nitrate and nitrite reduction. The LBL assembly as well as the changes in the HPA properties by immobilization has been characterized by electrochemical methods. The effects of the substituent ions, outer layers and the cationic moieties utilized for the films assembly of the developed film on the performances of nitrate electrocatalysis has been elucidated.
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Imar S. et al. Nitrate and Nitrite Electrocatalytic Reduction at Layer-by-Layer Films Composed of Dawson-type Heteropolyanions Mono-substituted with Transitional Metal Ions and Silver Nanoparticles // Electrochimica Acta. 2015. Vol. 184. pp. 323-330.
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Imar S., Yaqub M., Maccato C., Dickinson C., Laffir F., Vagin M. Y., McCormac T. Nitrate and Nitrite Electrocatalytic Reduction at Layer-by-Layer Films Composed of Dawson-type Heteropolyanions Mono-substituted with Transitional Metal Ions and Silver Nanoparticles // Electrochimica Acta. 2015. Vol. 184. pp. 323-330.
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TY - JOUR
DO - 10.1016/j.electacta.2015.10.082
UR - https://doi.org/10.1016/j.electacta.2015.10.082
TI - Nitrate and Nitrite Electrocatalytic Reduction at Layer-by-Layer Films Composed of Dawson-type Heteropolyanions Mono-substituted with Transitional Metal Ions and Silver Nanoparticles
T2 - Electrochimica Acta
AU - Imar, Shahzad
AU - Yaqub, M
AU - Maccato, Chiara
AU - Dickinson, Calum
AU - Laffir, Fathima
AU - Vagin, Mikhail Yu.
AU - McCormac, Timothy
PY - 2015
DA - 2015/12/01
PB - Elsevier
SP - 323-330
VL - 184
SN - 0013-4686
SN - 1873-3859
ER -
BibTex
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@article{2015_Imar,
author = {Shahzad Imar and M Yaqub and Chiara Maccato and Calum Dickinson and Fathima Laffir and Mikhail Yu. Vagin and Timothy McCormac},
title = {Nitrate and Nitrite Electrocatalytic Reduction at Layer-by-Layer Films Composed of Dawson-type Heteropolyanions Mono-substituted with Transitional Metal Ions and Silver Nanoparticles},
journal = {Electrochimica Acta},
year = {2015},
volume = {184},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.electacta.2015.10.082},
pages = {323--330},
doi = {10.1016/j.electacta.2015.10.082}
}