In-situ preparation and electrochemical characterization of submicron sized NaFePO4 cathode material for sodium-ion batteries
Publication type: Journal Article
Publication date: 2017-04-01
scimago Q1
wos Q1
SJR: 1.106
CiteScore: 10.6
Impact factor: 5.6
ISSN: 00134686, 18733859
General Chemical Engineering
Electrochemistry
Abstract
Submicron sized NaFePO 4 is successfully prepared in-situ by electrochemical delithiation of olivine type LiFePO 4 and subsequent sodium insertion in aprotic electrolyte. The composition dependence of the Gibbs energy and the entropy of sodiation is investigated by temperature dependent measurements of the equilibrium potential. The exchange current density and the sodium-ion diffusion coefficient of NaFePO 4 are systematically investigated as a function of the composition. Significant state of charge dependencies of the kinetic and thermodynamic parameters are found to correlate with phase transformations of the active material during charging and discharging. The results confirm the existence of a path dependence related to an asymmetric phase transformation behavior that was recently proposed in literature.
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68
Total citations:
68
Citations from 2025:
9
(13.24%)
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GOST
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Heubner C. et al. In-situ preparation and electrochemical characterization of submicron sized NaFePO4 cathode material for sodium-ion batteries // Electrochimica Acta. 2017. Vol. 233. pp. 78-84.
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Heubner C., Heiden S., Schneider M., Michaelis A. In-situ preparation and electrochemical characterization of submicron sized NaFePO4 cathode material for sodium-ion batteries // Electrochimica Acta. 2017. Vol. 233. pp. 78-84.
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TY - JOUR
DO - 10.1016/j.electacta.2017.02.107
UR - https://linkinghub.elsevier.com/retrieve/pii/S0013468617303833
TI - In-situ preparation and electrochemical characterization of submicron sized NaFePO4 cathode material for sodium-ion batteries
T2 - Electrochimica Acta
AU - Heubner, Christian
AU - Heiden, S
AU - Schneider, Michael
AU - Michaelis, Alexander
PY - 2017
DA - 2017/04/01
PB - Elsevier
SP - 78-84
VL - 233
SN - 0013-4686
SN - 1873-3859
ER -
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BibTex (up to 50 authors)
Copy
@article{2017_Heubner,
author = {Christian Heubner and S Heiden and Michael Schneider and Alexander Michaelis},
title = {In-situ preparation and electrochemical characterization of submicron sized NaFePO4 cathode material for sodium-ion batteries},
journal = {Electrochimica Acta},
year = {2017},
volume = {233},
publisher = {Elsevier},
month = {apr},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0013468617303833},
pages = {78--84},
doi = {10.1016/j.electacta.2017.02.107}
}