Electrochimica Acta, volume 286, pages 242-251

Gel polymer electrolyte based on p(acrylonitrile-maleic anhydride) for lithium ion battery

Yixuan Huang 1
Yun Huang 1
Liu Bo 1
Haijun Cao 2
Lei Zhao 1
Amin Song 1
Lin Yuanhua 1
Mingshan Wang 1
Xing Li 1
Zhang Zengping 3
Publication typeJournal Article
Publication date2018-10-01
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor6.6
ISSN00134686
General Chemical Engineering
Electrochemistry
Abstract
A polymer matrix of poly(acrylonitrile-maleic anhydride) (P(AN-MAH)) is used to prepare a novel porous membranes by phase inversion. The membranes are immersed into liquid electrolyte to form gel polymer electrolyte (GPE) used in lithium ion batteries (LIBs). The results indicate that P(AN-MAH) is successfully synthesized and the membrane of P(AN-MAH) copolymer with adding mass ratios of AN: MAH = 4:1 exhibits superior pore structure and better thermal stability compared with that of pure PAN membrane, which endows the corresponding GPE with excellent comprehensive performances: the considerable ionic conductivity (3.03 × 10−3 S cm−1 at room temperature), fine compatibility between GPE and electrode, eminent lithium transference number (tLi+ = 0.57), and high enough electrochemical stability potential (up to 5.4 V (vs. Li/Li+)). Accordingly, in constant current charging/discharging cycle, the prepared battery for the GPE also presents excellent initial discharge capacity, C-rate and cycling performances.

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GOST |
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GOST Copy
Huang Y. et al. Gel polymer electrolyte based on p(acrylonitrile-maleic anhydride) for lithium ion battery // Electrochimica Acta. 2018. Vol. 286. pp. 242-251.
GOST all authors (up to 50) Copy
Huang Y., Huang Y., Bo L., Cao H., Zhao L., Song A., Yuanhua L., Wang M., Li X., Zengping Z. Gel polymer electrolyte based on p(acrylonitrile-maleic anhydride) for lithium ion battery // Electrochimica Acta. 2018. Vol. 286. pp. 242-251.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.electacta.2018.08.024
UR - https://doi.org/10.1016/j.electacta.2018.08.024
TI - Gel polymer electrolyte based on p(acrylonitrile-maleic anhydride) for lithium ion battery
T2 - Electrochimica Acta
AU - Huang, Yixuan
AU - Huang, Yun
AU - Bo, Liu
AU - Cao, Haijun
AU - Zhao, Lei
AU - Song, Amin
AU - Yuanhua, Lin
AU - Wang, Mingshan
AU - Li, Xing
AU - Zengping, Zhang
PY - 2018
DA - 2018/10/01 00:00:00
PB - Elsevier
SP - 242-251
VL - 286
SN - 0013-4686
ER -
BibTex
Cite this
BibTex Copy
@article{2018_Huang,
author = {Yixuan Huang and Yun Huang and Liu Bo and Haijun Cao and Lei Zhao and Amin Song and Lin Yuanhua and Mingshan Wang and Xing Li and Zhang Zengping},
title = {Gel polymer electrolyte based on p(acrylonitrile-maleic anhydride) for lithium ion battery},
journal = {Electrochimica Acta},
year = {2018},
volume = {286},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.electacta.2018.08.024},
pages = {242--251},
doi = {10.1016/j.electacta.2018.08.024}
}
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