Energy Storage Materials, volume 23, pages 277-283

Covalent interfacial coupling for hybrid solid-state Li ion conductor

Jing Li ^{1, 2}

Hongwei Chen ³

Yanbin Shen ⁴

Chenji Hu ⁴

Zhenjie Cheng ⁴

Wei Lu ⁴

Y. Qiu ⁵

Liwei Chen ^{1, 6}

Hide authors affiliations Show authors affiliations: 6 affiliations

I-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou, 215123, China |

Shenzhen Engineering Lab of Flexible Transparent Conductive Films, School of Materials Science and Engineering, Harbin Institute of Technology, Shenzhen 518055, China |

College of Materials Science and Engineering,Huaqiao University,Xiamen 361021,China) |

⁴

i-Lab, CAS Center for Excellence in Nanoscience , Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences , Suzhou 215123 , China. |

⁵

Shenzhen Engineering Lab of Flexible Transparent Conductive Films, School of Materials Science and Engineering , Harbin Institute of Technology , Shenzhen 518055 , China. |

⁶

In-situ Center for Physical Sciences, School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai, 200240, China |

Publication type: Journal Article

Publication date: 2019-12-01

Elsevier

Journal: Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor: 20.4

ISSN: 24058297, 24058297

DOI: 10.1016/j.ensm.2019.05.002

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General Materials Science

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Solid electrolyte is the key component of any practical solid-state batteries. Although inorganic Li3PS4 electrolyte has been widely studied, this material is highly unstable in air, reactive towards Li metal, and difficult to process. These undesirable features have limited its application in solid state lithium batteries. In this work, a hybrid solid state electrolyte composed of β-Li3PS4 and poly(glycidyl methacrylate) is prepared through a controlled interfacial reaction between the polymer and the Li3PS4. The resulting hybrid electrolyte shows a good processability, i.e. it can be processed through simple slurry coating rather than conventional cold pressing or high-temperature sintering techniques. Furthermore, it exhibits improved air stability and decreased interfacial resistance with metallic lithium as compared with pure Li3PS4 electrolytes. More interestingly, this hybrid electrolyte exhibits a high ionic conductivity of 1.8 × 10−4 S/cm at room temperature, which is even slightly higher than the ionic conductivity of the pure β-Li3PS4. The new type of hybrid electrolyte will be highly promising for future applications in solid state batteries.

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Li J. et al. Covalent interfacial coupling for hybrid solid-state Li ion conductor // Energy Storage Materials. 2019. Vol. 23. pp. 277-283.

GOST all authors (up to 50) Copy

Li J., Chen H., Shen Y., Hu C., Cheng Z., Lu W., Qiu Y., Chen L. Covalent interfacial coupling for hybrid solid-state Li ion conductor // Energy Storage Materials. 2019. Vol. 23. pp. 277-283.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ensm.2019.05.002

UR - https://doi.org/10.1016/j.ensm.2019.05.002

TI - Covalent interfacial coupling for hybrid solid-state Li ion conductor

T2 - Energy Storage Materials

AU - Li, Jing

AU - Chen, Hongwei

AU - Shen, Yanbin

AU - Hu, Chenji

AU - Cheng, Zhenjie

AU - Lu, Wei

AU - Qiu, Y.

AU - Chen, Liwei

PY - 2019

DA - 2019/12/01 00:00:00

PB - Elsevier

SP - 277-283

VL - 23

SN - 2405-8297

ER -

BibTex

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BibTex Copy

@article{2019_Li,

author = {Jing Li and Hongwei Chen and Yanbin Shen and Chenji Hu and Zhenjie Cheng and Wei Lu and Y. Qiu and Liwei Chen},

title = {Covalent interfacial coupling for hybrid solid-state Li ion conductor},

journal = {Energy Storage Materials},

year = {2019},

volume = {23},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.ensm.2019.05.002},

pages = {277--283},

doi = {10.1016/j.ensm.2019.05.002}

}

Found error?

Publisher

Elsevier

Journal

Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor

20.4

ISSN

24058297 (Electronic)
24058297 (Print)