Energy Storage Materials, volume 24, pages 579-587

Lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide based single-ion polymer electrolyte with superior battery performance

Jianwei Zhang ¹

Shuanjin Wang ¹

Dongmei Han ²

Min Xiao ¹

Luyi Sun ³

Y. L. Meng ¹

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The Key Laboratory of Low-carbon Chemistry & Energy Conservation of Guangdong Province, State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials Science and Engineering, Sun Yat-Sen University,Guangzhou 510275,PR China |

School of Chemical Engineering and Technology, Sun Yat-sen Univeristy, Zhuhai, 519082, PR China |

, Polymer Program, Institute of Materials Science and Department of Chemical & Biomolecular Engineering, University of Connecticut, Storrs, Connecticut, 06269, United States |

Publication type: Journal Article

Publication date: 2020-01-01

Elsevier

Journal: Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor: 20.4

ISSN: 24058297, 24058297

DOI: 10.1016/j.ensm.2019.06.029

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General Materials Science

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

A novel single ion conducting polymer electrolyte is synthesized via a facile and efficient one-step ultraviolet initiated thiol-ene click reaction. The monomers of lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide, pentaerythritol tetrakis (2-mercaptoacetate) and pentaerythritol tetraacrylate are polymerized to be a crosslinked network structured polymer within a polypropylene nonwoven fabric supporting membrane by a photo-initiated thiol-ene click reaction. Upon solvent soaking, the obtained single ion conducting polymer electrolyte exhibits high ionic conductivity (0.84 mS cm−1 at room temperature), very high lithium ion transference number of 0.93, wide electrochemical window up to 5.2 V (vs. Li+/Li) and well compatibility with lithium metal anode. The corresponding LiFePO4/Li cell assembled with the prepared polymer electrolyte shows excellent rate capability and prominent cycling performance with the capacity retention rate of 83% after 400 cycles at 1 C. Therefore, the synthesized single ion conducting polymer electrolyte owns great potential for practical application in lithium ion batteries.

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	1 2 3 4 5 6 7
ACS Applied Energy Materials	ACS Applied Energy Materials, 7, 10.94% ACS Applied Energy Materials 7 publications, 10.94%
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Advanced Functional Materials	Advanced Functional Materials, 5, 7.81% Advanced Functional Materials 5 publications, 7.81%
Small	Small, 4, 6.25% Small 4 publications, 6.25%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 4, 6.25% Journal of Materials Chemistry A 4 publications, 6.25%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 3, 4.69% Journal of the Electrochemical Society 3 publications, 4.69%
Journal of Power Sources	Journal of Power Sources, 3, 4.69% Journal of Power Sources 3 publications, 4.69%
Polymers	Polymers, 2, 3.13% Polymers 2 publications, 3.13%
Ionics	Ionics, 2, 3.13% Ionics 2 publications, 3.13%
Applied Surface Science	Applied Surface Science, 2, 3.13% Applied Surface Science 2 publications, 3.13%
Journal of Membrane Science	Journal of Membrane Science, 2, 3.13% Journal of Membrane Science 2 publications, 3.13%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 3.13% ACS applied materials & interfaces 2 publications, 3.13%
ACS Energy Letters	ACS Energy Letters, 1, 1.56% ACS Energy Letters 1 publication, 1.56%
Journal of Materials Science: Materials in Electronics	Journal of Materials Science: Materials in Electronics, 1, 1.56% Journal of Materials Science: Materials in Electronics 1 publication, 1.56%
Chemical Reviews	Chemical Reviews, 1, 1.56% Chemical Reviews 1 publication, 1.56%
Materials	Materials, 1, 1.56% Materials 1 publication, 1.56%
Advanced Fiber Materials	Advanced Fiber Materials, 1, 1.56% Advanced Fiber Materials 1 publication, 1.56%
Electrochimica Acta	Electrochimica Acta, 1, 1.56% Electrochimica Acta 1 publication, 1.56%
Chinese Chemical Letters	Chinese Chemical Letters, 1, 1.56% Chinese Chemical Letters 1 publication, 1.56%
Nano Research	Nano Research, 1, 1.56% Nano Research 1 publication, 1.56%
Materials Today Nano	Materials Today Nano, 1, 1.56% Materials Today Nano 1 publication, 1.56%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 1.56% Journal of Colloid and Interface Science 1 publication, 1.56%
Macromolecular Rapid Communications	Macromolecular Rapid Communications, 1, 1.56% Macromolecular Rapid Communications 1 publication, 1.56%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 1.56% Energy & Environmental Materials 1 publication, 1.56%
Nanoscale	Nanoscale, 1, 1.56% Nanoscale 1 publication, 1.56%
Chemical Science	Chemical Science, 1, 1.56% Chemical Science 1 publication, 1.56%
Materials Chemistry Frontiers	Materials Chemistry Frontiers, 1, 1.56% Materials Chemistry Frontiers 1 publication, 1.56%
Advanced Materials	Advanced Materials, 1, 1.56% Advanced Materials 1 publication, 1.56%
Advanced Engineering Materials	Advanced Engineering Materials, 1, 1.56% Advanced Engineering Materials 1 publication, 1.56%
	1 2 3 4 5 6 7

Citations by publishers

	2 4 6 8 10 12 14 16 18 20
Elsevier	Elsevier, 19, 29.69% Elsevier 19 publications, 29.69%
Wiley	Wiley, 13, 20.31% Wiley 13 publications, 20.31%
American Chemical Society (ACS)	American Chemical Society (ACS), 11, 17.19% American Chemical Society (ACS) 11 publications, 17.19%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 7, 10.94% Royal Society of Chemistry (RSC) 7 publications, 10.94%
Springer Nature	Springer Nature, 5, 7.81% Springer Nature 5 publications, 7.81%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 4, 6.25% Multidisciplinary Digital Publishing Institute (MDPI) 4 publications, 6.25%
The Electrochemical Society	The Electrochemical Society, 3, 4.69% The Electrochemical Society 3 publications, 4.69%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.56% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.56%
	2 4 6 8 10 12 14 16 18 20

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Zhang J. et al. Lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide based single-ion polymer electrolyte with superior battery performance // Energy Storage Materials. 2020. Vol. 24. pp. 579-587.

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Zhang J., Wang S., Han D., Xiao M., Sun L., Meng Y. L. Lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide based single-ion polymer electrolyte with superior battery performance // Energy Storage Materials. 2020. Vol. 24. pp. 579-587.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ensm.2019.06.029

UR - https://doi.org/10.1016/j.ensm.2019.06.029

TI - Lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide based single-ion polymer electrolyte with superior battery performance

T2 - Energy Storage Materials

AU - Zhang, Jianwei

AU - Wang, Shuanjin

AU - Han, Dongmei

AU - Xiao, Min

AU - Sun, Luyi

AU - Meng, Y. L.

PY - 2020

DA - 2020/01/01 00:00:00

PB - Elsevier

SP - 579-587

VL - 24

SN - 2405-8297

ER -

BibTex

Cite this

BibTex Copy

@article{2020_Zhang,

author = {Jianwei Zhang and Shuanjin Wang and Dongmei Han and Min Xiao and Luyi Sun and Y. L. Meng},

title = {Lithium (4-styrenesulfonyl) (trifluoromethanesulfonyl) imide based single-ion polymer electrolyte with superior battery performance},

journal = {Energy Storage Materials},

year = {2020},

volume = {24},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.ensm.2019.06.029},

pages = {579--587},

doi = {10.1016/j.ensm.2019.06.029}

}

Found error?

Publisher

Elsevier

Journal

Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor

20.4

ISSN

24058297 (Electronic)
24058297 (Print)