Energy Storage Materials, volume 34, pages 388-416

Recent advances in organic-inorganic composite solid electrolytes for all-solid-state lithium batteries

Publication typeJournal Article
Publication date2021-01-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor20.4
ISSN24058297, 24058297
General Materials Science
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
With excellent safety and potentially high energy density, all-solid-state lithium batteries (ASSLBs) are expected to meet the needs of large-scale energy storage applications, and widely regarded as the next-generation battery technology to replace traditional lithium-ion batteries (LIBs). As one of the most important components in ASSLBs, solid-state electrolytes (SSEs) are the key to promoting the commercialization of ASSLBs. Ideal SSEs should at least possess excellent mechanical and electrochemical properties to enable ASSLBs to operate safely and stably for a long time at a relatively high rate. Unfortunately, solid polymer electrolytes (SPEs) and inorganic solid electrolytes (ISEs) are excluded because of their significant deficiency in electrochemical or mechanical properties. In contrast, organic-inorganic composite solid electrolytes (O-ICSEs) derived from incorporating inorganic fillers into SPEs can well balance the two properties through the synergy between the components, which are the most promising candidates for ASSLBs. Therefore, a timely summary of the latest research progress in the field of O-ICSEs is of great significance for designing O-ICSEs with better performance and early realizing the commercialization of ASSLBs. In this review, the enhancement mechanisms of the electrochemical performance for O-ICSEs are firstly discussed in detail, and the basic characteristics of effective fillers are determined. Then the latest research progress in recent five years of O-ICSEs based on polyethylene oxide (PEO), polyacrylonitrile (PAN) and polycarbonate matrix are highlighted, covering various fillers types, rational structural designs and main performance parameters. Finally, the existing problems and future research directions of O-ICSEs are summarized.

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GOST Copy
Cheng Z. et al. Recent advances in organic-inorganic composite solid electrolytes for all-solid-state lithium batteries // Energy Storage Materials. 2021. Vol. 34. pp. 388-416.
GOST all authors (up to 50) Copy
Cheng Z., Liu T., Zhao B., Shen F., Jin H., Han X. Recent advances in organic-inorganic composite solid electrolytes for all-solid-state lithium batteries // Energy Storage Materials. 2021. Vol. 34. pp. 388-416.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.ensm.2020.09.016
UR - https://doi.org/10.1016/j.ensm.2020.09.016
TI - Recent advances in organic-inorganic composite solid electrolytes for all-solid-state lithium batteries
T2 - Energy Storage Materials
AU - Cheng, Zhiwei
AU - Liu, Tong
AU - Zhao, Bin
AU - Shen, Fei
AU - Jin, H.Y.
AU - Han, Xiaogang
PY - 2021
DA - 2021/01/01 00:00:00
PB - Elsevier
SP - 388-416
VL - 34
SN - 2405-8297
SN - 2405-8297
ER -
BibTex
Cite this
BibTex Copy
@article{2021_Cheng,
author = {Zhiwei Cheng and Tong Liu and Bin Zhao and Fei Shen and H.Y. Jin and Xiaogang Han},
title = {Recent advances in organic-inorganic composite solid electrolytes for all-solid-state lithium batteries},
journal = {Energy Storage Materials},
year = {2021},
volume = {34},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.ensm.2020.09.016},
pages = {388--416},
doi = {10.1016/j.ensm.2020.09.016}
}
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