Energy Storage Materials, volume 37, pages 476-490
An advanced solid polymer electrolyte composed of poly(propylene carbonate) and mesoporous silica nanoparticles for use in all-solid-state lithium-ion batteries
Pravin N Didwal
1
,
Yashabanta N Singhbabu
1
,
Rakesh M. Verma
1
,
Bong Jun Sung
1
,
Gwi-Hak Lee
1
,
Jonghee Lee
1
,
Duck Rye Chang
2
,
Chan-Jin Park
1
Publication type: Journal Article
Publication date: 2021-05-01
Journal:
Energy Storage Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 20.4
ISSN: 24058297, 24058297
General Materials Science
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
• Electrolyte film is composed of PPC and highly mesoporous silica nanoparticles. • Composite solid polymer electrolyte (CSPE) shows high Li + transference number of 0.86. • Li/CSPE/Li cell possessed excellent stability over 1000 h with small overpotential. • Li/CSPE/LFP delivered capacity of 103 mAh g −1 at 1 C and rate capability up to 5 C. Composite solid polymer electrolytes (CSPEs) are promising candidates for replacing potentially hazardous organic liquid electrolytes used in Li ion batteries (LIBs). CSPEs are easy to process, have the ability to form films, and make better interfacial contact. However, their poor mechanical strength, low ionic conductivity, and long cycling stability limit their practical applications. Here, we demonstrate the fabrication of a cost-effective, flexible, self-standing, and highly stable CSPE using poly(propylene carbonate) (PPC) as the host matrix and highly mesoporous silica nanoparticles (MSNs) as the filler. The fabricated CSPE had a high ionic conductivity of approximately 8.5 × 10 −4 S cm −1 at 60°C, electrochemical potential stability up to approximately 4.8 V vs. Li/Li + , an ultra-high lithium transference number of approximately 0.86, impressive stability over 1000 h of Li stripping/plating, and an excellent electrode compatibility. With cyclability over 200 cycles and a negligible overpotential, the Li/CSPE/LFP cell delivered a reversible capacity of 171 and 103 mAh g −1 at 0.1 C and 1 C, respectively, with a good rate capability up to 5 C. The interaction of Li + with PPC and the MSNs is demonstrated by solid-state magic angle spinning nuclear magnetic resonance (MAS-NMR) and X-ray photoelectron spectroscopy (XPS) studies. The enhanced physico-electrochemical properties of the CSPE were attributed to the large MSNs-related surface area, which enables firm interaction with the PPC matrix and provides a less-tortuous polymer-ceramic phase for fast lithium ion transportation. The proposed MSNs-reinforced CSPE thus opens new possibilities for the fabrication and engineering of solid-state batteries.
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Citations by publishers
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5
10
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35
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1 publication, 1.16%
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5
10
15
20
25
30
35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Didwal P. N. et al. An advanced solid polymer electrolyte composed of poly(propylene carbonate) and mesoporous silica nanoparticles for use in all-solid-state lithium-ion batteries // Energy Storage Materials. 2021. Vol. 37. pp. 476-490.
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Didwal P. N., Singhbabu Y. N., Verma R. M., Sung B. J., Lee G., Lee J., Chang D. R., Park C. An advanced solid polymer electrolyte composed of poly(propylene carbonate) and mesoporous silica nanoparticles for use in all-solid-state lithium-ion batteries // Energy Storage Materials. 2021. Vol. 37. pp. 476-490.
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TY - JOUR
DO - 10.1016/j.ensm.2021.02.034
UR - https://doi.org/10.1016/j.ensm.2021.02.034
TI - An advanced solid polymer electrolyte composed of poly(propylene carbonate) and mesoporous silica nanoparticles for use in all-solid-state lithium-ion batteries
T2 - Energy Storage Materials
AU - Didwal, Pravin N
AU - Singhbabu, Yashabanta N
AU - Verma, Rakesh M.
AU - Sung, Bong Jun
AU - Lee, Gwi-Hak
AU - Lee, Jonghee
AU - Chang, Duck Rye
AU - Park, Chan-Jin
PY - 2021
DA - 2021/05/01 00:00:00
PB - Elsevier
SP - 476-490
VL - 37
SN - 2405-8297
SN - 2405-8297
ER -
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@article{2021_Didwal,
author = {Pravin N Didwal and Yashabanta N Singhbabu and Rakesh M. Verma and Bong Jun Sung and Gwi-Hak Lee and Jonghee Lee and Duck Rye Chang and Chan-Jin Park},
title = {An advanced solid polymer electrolyte composed of poly(propylene carbonate) and mesoporous silica nanoparticles for use in all-solid-state lithium-ion batteries},
journal = {Energy Storage Materials},
year = {2021},
volume = {37},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.ensm.2021.02.034},
pages = {476--490},
doi = {10.1016/j.ensm.2021.02.034}
}