Energy Storage Materials, volume 45, pages 1212-1219

Composite polymer electrolyte with three-dimensional ion transport channels constructed by NaCl template for solid-state lithium metal batteries

Publication typeJournal Article
Publication date2022-03-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor20.4
ISSN24058297, 24058297
General Materials Science
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
In order to meet the challenges brought by the low ionic conductivity of solid-state electrolytes (SSEs) and the growth of lithium dendrites in all-solid-state lithium metal batteries (ASSLMBs), the composite polymer electrolytes (CPEs) constructed by the combination of three-dimensional (3D) porous ceramics framework and polymers have been widely studied. However, there are still many challenges to preparation of 3D high-strength porous ceramics framework by a simple way. Here, we designed a 3D interconnected porous Li1.3Al0.3Ti1.7(PO4)3 (LATP) framework using NaCl as the template, which not only provides the fast transport channels for Li+ but also serves as a physical barrier to suppress the growth of Li dendrites. Benefiting from the enhanced mechanical and ionic conductivity of the 3D interconnected porous LATP framework, Li/Li symmetric cells based on the prepared CPE can cycle over 1000 h at 0.2 mA cm−2, 0.2 mAh cm−2 and 2000 h at 0.1 mA cm−2, 0.1 mAh cm−2. Moreover, all-solid-state LFP/Li with this 3D CPE demonstrates long-term stability cycles at 1 C.

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GOST Copy
Wang G. et al. Composite polymer electrolyte with three-dimensional ion transport channels constructed by NaCl template for solid-state lithium metal batteries // Energy Storage Materials. 2022. Vol. 45. pp. 1212-1219.
GOST all authors (up to 50) Copy
Wang G., Liu H., Liang Y., Wang C., Fan L. Composite polymer electrolyte with three-dimensional ion transport channels constructed by NaCl template for solid-state lithium metal batteries // Energy Storage Materials. 2022. Vol. 45. pp. 1212-1219.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.ensm.2021.11.021
UR - https://doi.org/10.1016/j.ensm.2021.11.021
TI - Composite polymer electrolyte with three-dimensional ion transport channels constructed by NaCl template for solid-state lithium metal batteries
T2 - Energy Storage Materials
AU - Wang, Guoxu
AU - Liu, Hong
AU - Liang, Yuhao
AU - Wang, Chao
AU - Fan, Li-Zhen
PY - 2022
DA - 2022/03/01 00:00:00
PB - Elsevier
SP - 1212-1219
VL - 45
SN - 2405-8297
SN - 2405-8297
ER -
BibTex
Cite this
BibTex Copy
@article{2022_Wang,
author = {Guoxu Wang and Hong Liu and Yuhao Liang and Chao Wang and Li-Zhen Fan},
title = {Composite polymer electrolyte with three-dimensional ion transport channels constructed by NaCl template for solid-state lithium metal batteries},
journal = {Energy Storage Materials},
year = {2022},
volume = {45},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.ensm.2021.11.021},
pages = {1212--1219},
doi = {10.1016/j.ensm.2021.11.021}
}
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