Energy Storage Materials, volume 45, pages 814-820

One-step fabrication of garnet solid electrolyte with integrated lithiophilic surface

Can Cui ¹

Ye Qi ¹

Zeng Cheng ¹

Shuhao Wang ¹

Xiaowei Xu ¹

Tianyou Zhai ¹

Huiqiao Li ¹

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State Key Laboratory of Materials Processing and Die and Mould Technology, School of Materials Sciences and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China |

Publication type: Journal Article

Publication date: 2022-03-01

Elsevier

Journal: Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor: 20.4

ISSN: 24058297, 24058297

DOI: 10.1016/j.ensm.2021.12.027

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General Materials Science

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Substituting nonflammable solid-state electrolytes for flammable liquid electrolyte is considered as the fundamental way to promote the safety of lithium metal batteries. However, the problem of poor interfacial contact between solid electrolyte and lithium has seriously hindered the development of solid-state batteries. This paper put forward an appealing strategy for constructing garnet solid electrolyte with a lithiophilic graphite interface via a one-step integrated spark plasma sintering method. With the existence of the integrated graphite modification layer, garnet turns lithiophobic into lithiophilic. And the lithiophilic graphite modification layer with high Li+-conductivity is conducive to homogenization of lithium-ion flux. Thus, the interfacial resistance decreases from 4351.6 to 26.2 Ω cm2 and accordingly the over-potential reduces from 500 to 30 mV, owing to the intimate interface contact, good interface compatibility and good lithium conductivity endowed by the integrated graphite modification layer. It shows excellent electrochemical stability for 900 h at 0.3 mA cm−2.

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Citations by journals

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ACS applied materials & interfaces	ACS applied materials & interfaces, 3, 12% ACS applied materials & interfaces 3 publications, 12%
Energy Storage Materials	Energy Storage Materials, 2, 8% Energy Storage Materials 2 publications, 8%
Advanced Functional Materials	Advanced Functional Materials, 2, 8% Advanced Functional Materials 2 publications, 8%
ACS Energy Letters	ACS Energy Letters, 1, 4% ACS Energy Letters 1 publication, 4%
Applied Physics Letters	Applied Physics Letters, 1, 4% Applied Physics Letters 1 publication, 4%
Journal of the Korean Ceramic Society	Journal of the Korean Ceramic Society, 1, 4% Journal of the Korean Ceramic Society 1 publication, 4%
Advanced Energy Materials	Advanced Energy Materials, 1, 4% Advanced Energy Materials 1 publication, 4%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 1, 4% Journal of Physical Chemistry C 1 publication, 4%
Small	Small, 1, 4% Small 1 publication, 4%
Nano Letters	Nano Letters, 1, 4% Nano Letters 1 publication, 4%
International Journal of Applied Ceramic Technology	International Journal of Applied Ceramic Technology, 1, 4% International Journal of Applied Ceramic Technology 1 publication, 4%
Nano-Micro Letters	Nano-Micro Letters, 1, 4% Nano-Micro Letters 1 publication, 4%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 4% Electrochemical Energy Reviews 1 publication, 4%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 4% Journal of Energy Chemistry 1 publication, 4%
ACS Materials Letters	ACS Materials Letters, 1, 4% ACS Materials Letters 1 publication, 4%
Materials Today Energy	Materials Today Energy, 1, 4% Materials Today Energy 1 publication, 4%
Energy and Environmental Science	Energy and Environmental Science, 1, 4% Energy and Environmental Science 1 publication, 4%
Nature Communications	Nature Communications, 1, 4% Nature Communications 1 publication, 4%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 4% Russian Chemical Reviews 1 publication, 4%
	1 2 3

Citations by publishers

	1 2 3 4 5 6 7
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 28% American Chemical Society (ACS) 7 publications, 28%
Elsevier	Elsevier, 5, 20% Elsevier 5 publications, 20%
Wiley	Wiley, 5, 20% Wiley 5 publications, 20%
Springer Nature	Springer Nature, 3, 12% Springer Nature 3 publications, 12%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 1, 4% American Institute of Physics (AIP) 1 publication, 4%
Korean Ceramic Society	Korean Ceramic Society, 1, 4% Korean Ceramic Society 1 publication, 4%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 4% Royal Society of Chemistry (RSC) 1 publication, 4%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 4% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 4%
	1 2 3 4 5 6 7

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Cui C. et al. One-step fabrication of garnet solid electrolyte with integrated lithiophilic surface // Energy Storage Materials. 2022. Vol. 45. pp. 814-820.

GOST all authors (up to 50) Copy

Cui C., Qi Y., Cheng Z., Wang S., Xu X., Zhai T., Li H. One-step fabrication of garnet solid electrolyte with integrated lithiophilic surface // Energy Storage Materials. 2022. Vol. 45. pp. 814-820.

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RIS Copy

TY - JOUR

DO - 10.1016/j.ensm.2021.12.027

UR - https://doi.org/10.1016/j.ensm.2021.12.027

TI - One-step fabrication of garnet solid electrolyte with integrated lithiophilic surface

T2 - Energy Storage Materials

AU - Cui, Can

AU - Qi, Ye

AU - Cheng, Zeng

AU - Wang, Shuhao

AU - Xu, Xiaowei

AU - Zhai, Tianyou

AU - Li, Huiqiao

PY - 2022

DA - 2022/03/01 00:00:00

PB - Elsevier

SP - 814-820

VL - 45

SN - 2405-8297

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Cui,

author = {Can Cui and Ye Qi and Zeng Cheng and Shuhao Wang and Xiaowei Xu and Tianyou Zhai and Huiqiao Li},

title = {One-step fabrication of garnet solid electrolyte with integrated lithiophilic surface},

journal = {Energy Storage Materials},

year = {2022},

volume = {45},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.ensm.2021.12.027},

pages = {814--820},

doi = {10.1016/j.ensm.2021.12.027}

}

Found error?

Publisher

Elsevier

Journal

Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor

20.4

ISSN

24058297 (Electronic)
24058297 (Print)