Energy Storage Materials, volume 46, pages 68-75

Smart construction of multifunctional Li1.5Al0.5Ge1.5(PO4)3|Li intermediate interfaces for solid-state batteries

JIAHAO YU ¹

Qi Liu ^{1, 2}

Hu Xia ¹

Shuwei Wang ¹

Junru Wu ¹

Bin Liang ¹

Cuiping Han ^{1, 3}

Feiyu Kang ¹

Baohua Li ¹

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Shenzhen Key Laboratory of Power Battery Safety and Shenzhen Geim Graphene Center, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, 518055, China |

College of Materials Science and Engineering, Hunan University, Changsha, 410082, Hunan, China |

Faculty of Materials Science and Engineering, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055, China |

Publication type: Journal Article

Publication date: 2022-04-01

Elsevier

Journal: Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor: 20.4

ISSN: 24058297, 24058297

DOI: 10.1016/j.ensm.2021.12.043

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General Materials Science

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Due to high ionic conductivity, low cost and excellent air stability, NASICON-type Li 1.5 Al 0.5 Ge 1.5 (PO) 4 (LAGP) electrolyte has been a promising candidate for high-performance solid-state batteries. Nevertheless, the poor interfacial compatibilities between LAGP and lithium (Li) metal (i.e., intrinsic instability of LAGP to metallic Li, growth of dendrite Li) retard its commercial application. Herein, a nano multifunctional LiF@Li-zinc (Zn) alloy layer consisting of electrically insulated but ionic conductive lithium fluoride (LiF) and Li-Zn alloy is introduced at the LAGP|Li interface (Z-LAGP) by in-situ conversion reactions. Such LiF@Li-Zn layer not only leads to stable and tight interface with low resistance and effective inhibition of side reactions, but also homogenizes the Li-ion flux with free of dendrite Li. Consequently, the Li|Z-LAGP|Li cells present the improved critical current density as high as 2.0 mA cm −2 , stable cycles with longer than 1000 h at 0.1 mA cm −2 , and as well as superior cycling performance from 0.1 to 0.5 mA cm −2 with stable overpotential. What is more, the solid-state batteries of Li|Z-LAGP|LiFePO 4 show the good cycle stability with highly reversible capacity (>150 mA h g − 1 ) at 0.1 C under room temperature. This work highlights a rational design for the robust LAGP|Li interface and a novel strategy to optimizing interfacial compatibilities.

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Citations by journals

	1 2 3 4 5
Advanced Energy Materials	Advanced Energy Materials, 5, 10% Advanced Energy Materials 5 publications, 10%
Energy Storage Materials	Energy Storage Materials, 3, 6% Energy Storage Materials 3 publications, 6%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 3, 6% Journal of Materials Chemistry A 3 publications, 6%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 3, 6% Angewandte Chemie - International Edition 3 publications, 6%
Angewandte Chemie	Angewandte Chemie, 3, 6% Angewandte Chemie 3 publications, 6%
Journal of Power Sources	Journal of Power Sources, 2, 4% Journal of Power Sources 2 publications, 4%
Advanced Functional Materials	Advanced Functional Materials, 2, 4% Advanced Functional Materials 2 publications, 4%
ACS Nano	ACS Nano, 2, 4% ACS Nano 2 publications, 4%
Journal of Energy Storage	Journal of Energy Storage, 2, 4% Journal of Energy Storage 2 publications, 4%
Chemistry Letters	Chemistry Letters, 1, 2% Chemistry Letters 1 publication, 2%
EcoMat	EcoMat, 1, 2% EcoMat 1 publication, 2%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2% ACS Applied Energy Materials 1 publication, 2%
Journal of Solid State Chemistry	Journal of Solid State Chemistry, 1, 2% Journal of Solid State Chemistry 1 publication, 2%
Current Opinion in Electrochemistry	Current Opinion in Electrochemistry, 1, 2% Current Opinion in Electrochemistry 1 publication, 2%
Composites Part B: Engineering	Composites Part B: Engineering, 1, 2% Composites Part B: Engineering 1 publication, 2%
Nano Research	Nano Research, 1, 2% Nano Research 1 publication, 2%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 1, 2% Physical Chemistry Chemical Physics 1 publication, 2%
Nano Energy	Nano Energy, 1, 2% Nano Energy 1 publication, 2%
Polymers	Polymers, 1, 2% Polymers 1 publication, 2%
Batteries	Batteries, 1, 2% Batteries 1 publication, 2%
Applied Surface Science	Applied Surface Science, 1, 2% Applied Surface Science 1 publication, 2%
ChemSusChem	ChemSusChem, 1, 2% ChemSusChem 1 publication, 2%
Next Nanotechnology	Next Nanotechnology, 1, 2% Next Nanotechnology 1 publication, 2%
Chemistry - A European Journal	Chemistry - A European Journal, 1, 2% Chemistry - A European Journal 1 publication, 2%
Chemical Science	Chemical Science, 1, 2% Chemical Science 1 publication, 2%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 2% Journal of Colloid and Interface Science 1 publication, 2%
Progress in Natural Science: Materials International	Progress in Natural Science: Materials International, 1, 2% Progress in Natural Science: Materials International 1 publication, 2%
Nature Reviews Materials	Nature Reviews Materials, 1, 2% Nature Reviews Materials 1 publication, 2%
Progress in Materials Science	Progress in Materials Science, 1, 2% Progress in Materials Science 1 publication, 2%
	1 2 3 4 5

Citations by publishers

	2 4 6 8 10 12 14 16 18
Wiley	Wiley, 17, 34% Wiley 17 publications, 34%
Elsevier	Elsevier, 17, 34% Elsevier 17 publications, 34%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 5, 10% Royal Society of Chemistry (RSC) 5 publications, 10%
American Chemical Society (ACS)	American Chemical Society (ACS), 4, 8% American Chemical Society (ACS) 4 publications, 8%
Springer Nature	Springer Nature, 2, 4% Springer Nature 2 publications, 4%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 4% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 4%
The Chemical Society of Japan	The Chemical Society of Japan, 1, 2% The Chemical Society of Japan 1 publication, 2%
American Physical Society (APS)	American Physical Society (APS), 1, 2% American Physical Society (APS) 1 publication, 2%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2%
	2 4 6 8 10 12 14 16 18

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YU J. et al. Smart construction of multifunctional Li1.5Al0.5Ge1.5(PO4)3|Li intermediate interfaces for solid-state batteries // Energy Storage Materials. 2022. Vol. 46. pp. 68-75.

GOST all authors (up to 50) Copy

YU J., Liu Q., Xia H., Wang S., Wu J., Liang B., Han C., Kang F., Li B. Smart construction of multifunctional Li1.5Al0.5Ge1.5(PO4)3|Li intermediate interfaces for solid-state batteries // Energy Storage Materials. 2022. Vol. 46. pp. 68-75.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ensm.2021.12.043

UR - https://doi.org/10.1016/j.ensm.2021.12.043

TI - Smart construction of multifunctional Li1.5Al0.5Ge1.5(PO4)3|Li intermediate interfaces for solid-state batteries

T2 - Energy Storage Materials

AU - YU, JIAHAO

AU - Liu, Qi

AU - Xia, Hu

AU - Wang, Shuwei

AU - Wu, Junru

AU - Liang, Bin

AU - Han, Cuiping

AU - Kang, Feiyu

AU - Li, Baohua

PY - 2022

DA - 2022/04/01 00:00:00

PB - Elsevier

SP - 68-75

VL - 46

SN - 2405-8297

ER -

BibTex

Cite this

BibTex Copy

@article{2022_YU,

author = {JIAHAO YU and Qi Liu and Hu Xia and Shuwei Wang and Junru Wu and Bin Liang and Cuiping Han and Feiyu Kang and Baohua Li},

title = {Smart construction of multifunctional Li1.5Al0.5Ge1.5(PO4)3|Li intermediate interfaces for solid-state batteries},

journal = {Energy Storage Materials},

year = {2022},

volume = {46},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016/j.ensm.2021.12.043},

pages = {68--75},

doi = {10.1016/j.ensm.2021.12.043}

}

Found error?

Publisher

Elsevier

Journal

Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor

20.4

ISSN

24058297 (Electronic)
24058297 (Print)