Energy Storage Materials, volume 48, pages 375-383

Topology crafting of polyvinylidene difluoride electrolyte creates ultra-long cycling high-voltage lithium metal solid-state batteries

Jinshuo Mi ¹

Jiabin Ma ¹

Likun Chen ¹

Chen Lai ²

Yang Ke ¹

Jie Biao ¹

Heyi Xia ¹

Xin Song ³

Wei Lv ¹

Guiming Zhong ⁴

Yan-bing He ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

Shenzhen Geim Graphene Center, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen 518055, China |

Key Lab of Advanced Functional Materials, Ministry of Education, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100084, China |

Department of Chemical and Materials Engineering, The University of Auckland, Auckland 1142, New Zealand |

⁴

Laboratory of Advanced Spectro-Electrochemistry and Li-Ion Batteries, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China |

Publication type: Journal Article

Publication date: 2022-06-01

Elsevier

Journal: Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor: 20.4

ISSN: 24058297, 24058297

DOI: 10.1016/j.ensm.2022.02.048

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General Materials Science

Energy Engineering and Power Technology

Renewable Energy, Sustainability and the Environment

Abstract

Solid-state polymer electrolytes (SPEs) present poor anti-oxidation ability, low ionic conductivity and high flammability, which greatly restrict their applications in high-voltage solid-state lithium metal batteries. Herein, we uniformly graft the lithium phenyl phosphate (LPPO) on polyvinylidene difluoride (PVDF) by dehydrofluorination and Friedel-Crafts alkylation reactions to create a multifunctional PVDF-LPPO SPE with branched topology. The LPPO serves as a single ion conductor, flame retardant and cathode electrolyte interface formation agent not only greatly improves the ionic conductivity, fireproof property and electrochemical stability of SPE, but also remarkably suppresses the side reactions with both cathode and lithium metal anode. An additional and uniform Li-ion transmission path is constructed by LPPO to remarkably reduce the activation energy and enhance the lithium-ion transference number of PVDF-LPPO SPE. The solid-state LiNi 0.8 Co 0.1 Mn 0.1 O 2 ||PVDF-LPPO||Li batteries stably cycle for 1550 times between 2.8 and 4.3 V at 1 C and 1000 times under a high charging voltage of 4.5 V. The transformation of layered structure to rock-salt phase of NCM811 particles is greatly suppressed during long cycling by a stable and uniform LPPO derived cathode electrolyte interface. This work provides a precise operation method for modifying structure of polymer electrolyte to achieve outstanding special properties of lithium metal solid-state batteries. A multifunctional solid-state polymer electrolyte (SPE) with branched topology is developed by accurately operate the molecular structure of PVDF and uniformly graft the phosphorus derivatives on its chains. The high-voltage lithium metal batteries assembled present good safety performance, excellent ions transport capability and ultra-long cyclic stability even charged to 4.5 V.

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ACS applied materials & interfaces	ACS applied materials & interfaces, 4, 5.06% ACS applied materials & interfaces 4 publications, 5.06%
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Nano Research	Nano Research, 3, 3.8% Nano Research 3 publications, 3.8%
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Chemical Engineering Journal	Chemical Engineering Journal, 2, 2.53% Chemical Engineering Journal 2 publications, 2.53%
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Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 1.27% Journal of Colloid and Interface Science 1 publication, 1.27%
Materials Today Physics	Materials Today Physics, 1, 1.27% Materials Today Physics 1 publication, 1.27%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 1.27% Journal of Energy Chemistry 1 publication, 1.27%
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PNAS Nexus	PNAS Nexus, 1, 1.27% PNAS Nexus 1 publication, 1.27%
Nature Communications	Nature Communications, 1, 1.27% Nature Communications 1 publication, 1.27%
Small Methods	Small Methods, 1, 1.27% Small Methods 1 publication, 1.27%
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Citations by publishers

	5 10 15 20 25
Wiley	Wiley, 25, 31.65% Wiley 25 publications, 31.65%
Elsevier	Elsevier, 23, 29.11% Elsevier 23 publications, 29.11%
American Chemical Society (ACS)	American Chemical Society (ACS), 11, 13.92% American Chemical Society (ACS) 11 publications, 13.92%
Springer Nature	Springer Nature, 8, 10.13% Springer Nature 8 publications, 10.13%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 6, 7.59% Royal Society of Chemistry (RSC) 6 publications, 7.59%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 3, 3.8% Multidisciplinary Digital Publishing Institute (MDPI) 3 publications, 3.8%
Oxford University Press	Oxford University Press, 1, 1.27% Oxford University Press 1 publication, 1.27%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.27% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.27%
	5 10 15 20 25

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Mi J. et al. Topology crafting of polyvinylidene difluoride electrolyte creates ultra-long cycling high-voltage lithium metal solid-state batteries // Energy Storage Materials. 2022. Vol. 48. pp. 375-383.

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Mi J., Ma J., Chen L., Lai C., Yang Ke, Biao J., Xia H., Song X., Lv W., Zhong G., He Y. Topology crafting of polyvinylidene difluoride electrolyte creates ultra-long cycling high-voltage lithium metal solid-state batteries // Energy Storage Materials. 2022. Vol. 48. pp. 375-383.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ensm.2022.02.048

UR - https://doi.org/10.1016/j.ensm.2022.02.048

TI - Topology crafting of polyvinylidene difluoride electrolyte creates ultra-long cycling high-voltage lithium metal solid-state batteries

T2 - Energy Storage Materials

AU - Mi, Jinshuo

AU - Ma, Jiabin

AU - Chen, Likun

AU - Lai, Chen

AU - Yang Ke

AU - Biao, Jie

AU - Xia, Heyi

AU - Song, Xin

AU - Lv, Wei

AU - Zhong, Guiming

AU - He, Yan-bing

PY - 2022

DA - 2022/06/01 00:00:00

PB - Elsevier

SP - 375-383

VL - 48

SN - 2405-8297

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Mi,

author = {Jinshuo Mi and Jiabin Ma and Likun Chen and Chen Lai and Yang Ke and Jie Biao and Heyi Xia and Xin Song and Wei Lv and Guiming Zhong and Yan-bing He},

title = {Topology crafting of polyvinylidene difluoride electrolyte creates ultra-long cycling high-voltage lithium metal solid-state batteries},

journal = {Energy Storage Materials},

year = {2022},

volume = {48},

publisher = {Elsevier},

month = {jun},

url = {https://doi.org/10.1016/j.ensm.2022.02.048},

pages = {375--383},

doi = {10.1016/j.ensm.2022.02.048}

}

Found error?

Publisher

Elsevier

Journal

Energy Storage Materials

Quartile SCImago

Quartile WOS

Impact factor

20.4

ISSN

24058297 (Electronic)
24058297 (Print)