European Polymer Journal

, volume 41 , issue 12 , pages 2861-2866

Polymerization of hydroxyl functional polypropylene by metallocene catalysis

Santeri Paavola ¹

Barbro Löfgren ¹

J. Seppälä ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Polymer Technology, Helsinki University of Technology, P.O. Box 6100, FIN‐02015 HUT, Finland |

Publication type: Journal Article

Publication date: 2005-12-01

Elsevier

European Polymer Journal

scimago Q1

wos Q1

SJR: 1.076

CiteScore: 10.2

Impact factor: 6.3

ISSN: 00143057, 18731945

DOI: 10.1016/j.eurpolymj.2005.05.014

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Materials Chemistry

Organic Chemistry

General Physics and Astronomy

Polymers and Plastics

Abstract

Propylene was copolymerized with 10-undecen-1-ol with use of dimethylsilanyl-bis-(2-methyl-4-phenyl-1-indenyl)zirconium dichloride as catalyst activated with methylaluminoxane (MAO) and triisobutylaluminum (TIBA). Comonomer incorporations as high as 2.0 mol% or 8.2 wt% were obtained without serious activity losses. Concentration of MAO, aluminum/comonomer ratio and pressure had some effect on polymerization activity and yield. However, changing the proportion of MAO in the cocatalyst mixture of MAO and TIBA proved to be most efficient way to enhance polymerization activity. Still, the result was a compromise between high functionality content, polymerization activity and molecular weight.

Found

1 citation

Ilyin Sergey

PhD in Chemistry

145 publications, 3 022 citations, 623 reviews

h-index: 34

A.V. Topchiev Institute of Petrochemical Synthesis RAS

High molecular weight compounds

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Paavola S., Löfgren B., Seppälä J. Polymerization of hydroxyl functional polypropylene by metallocene catalysis // European Polymer Journal. 2005. Vol. 41. No. 12. pp. 2861-2866.

GOST all authors (up to 50) Copy

Paavola S., Löfgren B., Seppälä J. Polymerization of hydroxyl functional polypropylene by metallocene catalysis // European Polymer Journal. 2005. Vol. 41. No. 12. pp. 2861-2866.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.eurpolymj.2005.05.014

UR - https://doi.org/10.1016/j.eurpolymj.2005.05.014

TI - Polymerization of hydroxyl functional polypropylene by metallocene catalysis

T2 - European Polymer Journal

AU - Paavola, Santeri

AU - Löfgren, Barbro

AU - Seppälä, J.

PY - 2005

DA - 2005/12/01

PB - Elsevier

SP - 2861-2866

IS - 12

VL - 41

SN - 0014-3057

SN - 1873-1945

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2005_Paavola,

author = {Santeri Paavola and Barbro Löfgren and J. Seppälä},

title = {Polymerization of hydroxyl functional polypropylene by metallocene catalysis},

journal = {European Polymer Journal},

year = {2005},

volume = {41},

publisher = {Elsevier},

month = {dec},

url = {https://doi.org/10.1016/j.eurpolymj.2005.05.014},

number = {12},

pages = {2861--2866},

doi = {10.1016/j.eurpolymj.2005.05.014}

}

MLA

Cite this

MLA Copy

Paavola, Santeri, et al. “Polymerization of hydroxyl functional polypropylene by metallocene catalysis.” European Polymer Journal, vol. 41, no. 12, Dec. 2005, pp. 2861-2866. https://doi.org/10.1016/j.eurpolymj.2005.05.014.

Publisher

Elsevier

Journal

European Polymer Journal

scimago Q1

wos Q1

SJR

1.076

CiteScore

10.2

Impact factor

6.3

ISSN

00143057 (Print)

18731945