Synthesis of poly(10-undecene-1-ol) by metallocene-catalyzed polymerization
Ulrich Schulze
1
,
Matthias Johannsen
1
,
Robert Haschick
1
,
Hartmut Komber
1
,
Albena Lederer
1
,
Brigitte Voit
1
Тип публикации: Journal Article
Дата публикации: 2010-03-01
scimago Q1
wos Q1
БС1
SJR: 1.076
CiteScore: 10.2
Impact factor: 6.3
ISSN: 00143057, 18731945
Materials Chemistry
Organic Chemistry
General Physics and Astronomy
Polymers and Plastics
Краткое описание
Poly(10-undecene-1-ol)s as precursors for potential polar macromonomers were synthesized by metallocene-catalyzed polymerization. For the use as macromonomers, polymerizable terminal double bonds are an important requirement and thus, the investigation of the end groups in the polymers was the main focus of this study. The influence of the catalyst and polymerization conditions on the chain length of the polymer backbone, the monomer conversion as well as the end group characteristics were analyzed. It was possible to find conditions for preparing poly(10-undecene-1-ol)s with terminal double bonds using the catalyst system Cp2ZrCl2/MAO. Two other chosen catalysts produced mainly internal double bonds. The poly(10-undecene-1-ol)s could be prepared as atactic or isotactic-rich materials depending on the catalyst used.
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Schulze U. et al. Synthesis of poly(10-undecene-1-ol) by metallocene-catalyzed polymerization // European Polymer Journal. 2010. Vol. 46. No. 3. pp. 578-586.
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Schulze U., Johannsen M., Haschick R., Komber H., Lederer A., Voit B. Synthesis of poly(10-undecene-1-ol) by metallocene-catalyzed polymerization // European Polymer Journal. 2010. Vol. 46. No. 3. pp. 578-586.
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TY - JOUR
DO - 10.1016/j.eurpolymj.2009.11.012
UR - https://doi.org/10.1016/j.eurpolymj.2009.11.012
TI - Synthesis of poly(10-undecene-1-ol) by metallocene-catalyzed polymerization
T2 - European Polymer Journal
AU - Schulze, Ulrich
AU - Johannsen, Matthias
AU - Haschick, Robert
AU - Komber, Hartmut
AU - Lederer, Albena
AU - Voit, Brigitte
PY - 2010
DA - 2010/03/01
PB - Elsevier
SP - 578-586
IS - 3
VL - 46
SN - 0014-3057
SN - 1873-1945
ER -
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@article{2010_Schulze,
author = {Ulrich Schulze and Matthias Johannsen and Robert Haschick and Hartmut Komber and Albena Lederer and Brigitte Voit},
title = {Synthesis of poly(10-undecene-1-ol) by metallocene-catalyzed polymerization},
journal = {European Polymer Journal},
year = {2010},
volume = {46},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.eurpolymj.2009.11.012},
number = {3},
pages = {578--586},
doi = {10.1016/j.eurpolymj.2009.11.012}
}
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MLA
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Schulze, Ulrich, et al. “Synthesis of poly(10-undecene-1-ol) by metallocene-catalyzed polymerization.” European Polymer Journal, vol. 46, no. 3, Mar. 2010, pp. 578-586. https://doi.org/10.1016/j.eurpolymj.2009.11.012.