European Polymer Journal

, том 49 , издание 1 , страницы 147-155

Cocatalyst effect in propylene polymerization reactions with post-metallocene catalysts

Тип публикации: Journal Article

Дата публикации: 2013-01-01

Elsevier

European Polymer Journal

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wos Q1

БС1

SJR: 1.076

CiteScore: 10.2

Impact factor: 6.3

ISSN: 00143057, 18731945

DOI: 10.1016/j.eurpolymj.2012.10.018

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Materials Chemistry

Organic Chemistry

General Physics and Astronomy

Polymers and Plastics

Краткое описание

Effect of cocatalysts on the performance of three post-metallocene catalysts based on complexes I–III in Scheme 1 is studied by comparing their activity in the presence of two cocatalysts, MAO and a combination of AlEt2Cl and MgBu2, in propylene polymerization reactions. The second cocatalyst produces significantly more active catalysts. Analysis of GPC, DSC and 13C NMR data for the polymers suggests that the activity increase is caused by the formation of new types of active centers. Some of the new centers are isospecific and operate according to the enantiomorphic stereocontrol mechanism.

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Rishina L. A. et al. Cocatalyst effect in propylene polymerization reactions with post-metallocene catalysts // European Polymer Journal. 2013. Vol. 49. No. 1. pp. 147-155.

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Rishina L. A., Galashina N. M., Gagieva S. C., Khrustalev V. N., Kissin Y. V. Cocatalyst effect in propylene polymerization reactions with post-metallocene catalysts // European Polymer Journal. 2013. Vol. 49. No. 1. pp. 147-155.

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TY - JOUR

DO - 10.1016/j.eurpolymj.2012.10.018

UR - https://doi.org/10.1016/j.eurpolymj.2012.10.018

TI - Cocatalyst effect in propylene polymerization reactions with post-metallocene catalysts

T2 - European Polymer Journal

AU - Rishina, L A

AU - Galashina, N M

AU - Gagieva, Svetlana Ch

AU - Khrustalev, Victor N.

AU - Kissin, Yury V

PY - 2013

DA - 2013/01/01

PB - Elsevier

SP - 147-155

IS - 1

VL - 49

SN - 0014-3057

SN - 1873-1945

ER -

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@article{2013_Rishina,

author = {L A Rishina and N M Galashina and Svetlana Ch Gagieva and Victor N. Khrustalev and Yury V Kissin},

title = {Cocatalyst effect in propylene polymerization reactions with post-metallocene catalysts},

journal = {European Polymer Journal},

year = {2013},

volume = {49},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.eurpolymj.2012.10.018},

number = {1},

pages = {147--155},

doi = {10.1016/j.eurpolymj.2012.10.018}

}

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Rishina, L. A., et al. “Cocatalyst effect in propylene polymerization reactions with post-metallocene catalysts.” European Polymer Journal, vol. 49, no. 1, Jan. 2013, pp. 147-155. https://doi.org/10.1016/j.eurpolymj.2012.10.018.