Synthesis and characterization of statistical copolymers of trimethylene carbonate and l-lactide using Mg(II)/Ti(IV) mixed alkoxides as initiator system
Publication type: Journal Article
Publication date: 2014-08-01
scimago Q1
wos Q1
SJR: 1.076
CiteScore: 10.2
Impact factor: 6.3
ISSN: 00143057, 18731945
Materials Chemistry
Organic Chemistry
General Physics and Astronomy
Polymers and Plastics
Abstract
Copolymers of trimethylene carbonate and l -lactide with distinct compositions were prepared in bulk employing a novel initiator comprising two biocompatible metals. The NMR analyses showed that the initiator, Catylen® S200, has preference for l -lactide incorporation during the copolymerization, which is attested by the deviations in copolymer compositions compared to the monomers feed ratios and differences between the calculated and the observed average block lengths of lactide units. Nevertheless, the presence of higher contents of trimethylene carbonate led to a higher degree of transesterification, furnishing a copolymer with composition close to a true statistical copolymer when the content of carbonate trimethylene is 51 wt%. The effects of the composition in the thermal properties and the crystallinity of the copolymers were also investigated by DSC and WAXD respectively.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Polymer Bulletin
2 publications, 14.29%
|
|
|
European Polymer Journal
1 publication, 7.14%
|
|
|
Polymer Testing
1 publication, 7.14%
|
|
|
Inorganic Chemistry Communication
1 publication, 7.14%
|
|
|
Materials Today Communications
1 publication, 7.14%
|
|
|
Polymers for Advanced Technologies
1 publication, 7.14%
|
|
|
RSC Advances
1 publication, 7.14%
|
|
|
Chemical Communications
1 publication, 7.14%
|
|
|
Brazilian Journal of Medical and Biological Research
1 publication, 7.14%
|
|
|
Organometallics
1 publication, 7.14%
|
|
|
Canadian Journal of Chemistry
1 publication, 7.14%
|
|
|
Mendeleev Communications
1 publication, 7.14%
|
|
|
1
2
|
Publishers
|
1
2
3
4
5
|
|
|
Elsevier
5 publications, 35.71%
|
|
|
Springer Nature
2 publications, 14.29%
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 14.29%
|
|
|
Wiley
1 publication, 7.14%
|
|
|
1 publication, 7.14%
|
|
|
American Chemical Society (ACS)
1 publication, 7.14%
|
|
|
Canadian Science Publishing
1 publication, 7.14%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 7.14%
|
|
|
1
2
3
4
5
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
14
Total citations:
14
Citations from 2025:
2
(14.29%)
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Silvino A. C. et al. Synthesis and characterization of statistical copolymers of trimethylene carbonate and l-lactide using Mg(II)/Ti(IV) mixed alkoxides as initiator system // European Polymer Journal. 2014. Vol. 57. pp. 66-74.
GOST all authors (up to 50)
Copy
Silvino A. C., Rodrigues A. M., De Jesus K. F., Dias M. L. Synthesis and characterization of statistical copolymers of trimethylene carbonate and l-lactide using Mg(II)/Ti(IV) mixed alkoxides as initiator system // European Polymer Journal. 2014. Vol. 57. pp. 66-74.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.eurpolymj.2014.05.001
UR - https://doi.org/10.1016/j.eurpolymj.2014.05.001
TI - Synthesis and characterization of statistical copolymers of trimethylene carbonate and l-lactide using Mg(II)/Ti(IV) mixed alkoxides as initiator system
T2 - European Polymer Journal
AU - Silvino, Alexandre C.
AU - Rodrigues, André Machado
AU - De Jesus, Katherine Fernandes
AU - Dias, M. L.
PY - 2014
DA - 2014/08/01
PB - Elsevier
SP - 66-74
VL - 57
SN - 0014-3057
SN - 1873-1945
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Silvino,
author = {Alexandre C. Silvino and André Machado Rodrigues and Katherine Fernandes De Jesus and M. L. Dias},
title = {Synthesis and characterization of statistical copolymers of trimethylene carbonate and l-lactide using Mg(II)/Ti(IV) mixed alkoxides as initiator system},
journal = {European Polymer Journal},
year = {2014},
volume = {57},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.eurpolymj.2014.05.001},
pages = {66--74},
doi = {10.1016/j.eurpolymj.2014.05.001}
}