Solubility of ethylene in toluene, norbornene, and toluene+norbornene mixture
2
R&D Center, Polyplastics Co. Ltd., 973 Miyajima, Fuji, Shizuoka 416-8533, Japan
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Publication type: Journal Article
Publication date: 2013-04-01
scimago Q2
wos Q2
SJR: 0.578
CiteScore: 5.4
Impact factor: 2.7
ISSN: 03783812, 18790224
Physical and Theoretical Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
The solubility of monomer gases in polymer solutions is important to analyze and optimize polymerization processes. This work investigated the solubilities of ethylene in organic solvents that are related to the production of cyclic olefin copolymers. Solubilities of ethylene in toluene, norbornene and toluene/norbornene mixtures were measured at temperatures of 323, 343, and 363 K and at pressures up to 5.7 MPa. The solubilities of ethylene increased with increasing pressure and they increased with decreasing temperature. The Peng–Robinson equation of state could correlate the experimental solubilities of binary and ternary systems with binary interaction parameters to within about 3%.
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14
Total citations:
14
Citations from 2024:
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(14.28%)
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Sato Y. et al. Solubility of ethylene in toluene, norbornene, and toluene+norbornene mixture // Fluid Phase Equilibria. 2013. Vol. 344. pp. 112-116.
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Sato Y., Hosaka N., Inomata H., Kanaka K. Solubility of ethylene in toluene, norbornene, and toluene+norbornene mixture // Fluid Phase Equilibria. 2013. Vol. 344. pp. 112-116.
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RIS
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TY - JOUR
DO - 10.1016/j.fluid.2013.01.023
UR - https://doi.org/10.1016/j.fluid.2013.01.023
TI - Solubility of ethylene in toluene, norbornene, and toluene+norbornene mixture
T2 - Fluid Phase Equilibria
AU - Sato, Yoshiyuki
AU - Hosaka, Naoki
AU - Inomata, Hiroshi
AU - Kanaka, Keiichi
PY - 2013
DA - 2013/04/01
PB - Elsevier
SP - 112-116
VL - 344
SN - 0378-3812
SN - 1879-0224
ER -
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BibTex (up to 50 authors)
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@article{2013_Sato,
author = {Yoshiyuki Sato and Naoki Hosaka and Hiroshi Inomata and Keiichi Kanaka},
title = {Solubility of ethylene in toluene, norbornene, and toluene+norbornene mixture},
journal = {Fluid Phase Equilibria},
year = {2013},
volume = {344},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.fluid.2013.01.023},
pages = {112--116},
doi = {10.1016/j.fluid.2013.01.023}
}