Petroleum-containing residue processing via co-catalyzed pyrolysis
Publication type: Journal Article
Publication date: 2017-06-01
scimago Q1
wos Q1
SJR: 1.614
CiteScore: 14.2
Impact factor: 7.5
ISSN: 00162361, 18737153
Organic Chemistry
General Chemical Engineering
Energy Engineering and Power Technology
Fuel Technology
Abstract
This paper is devoted to the study of oil-containing residue (oil-slime) pyrolysis process in the presence of cobalt chloride as a catalyst. A mixture consisting of crude oil (20 wt.%) and silica (80 wt.%) was used as a model substrate. The pyrolysis process carried out at a temperature 500 °C in nitrogen atmosphere in the presence of 5 wt.% of CoCl2 allowed obtaining an optimal gaseous, liquid and solid product distribution. Moreover the comparison of liquid and solid pyrolysis products composition with those obtained in non-catalytic process was done. It was found that the use of CoCl2 increases the calorific value of both gaseous and liquid products due to the increase in hydrocarbon formation. Pyrolysis solid residue was found to consist of silica particles coated with pyrolysis graphite and can be used as a valuable sorbent.
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GOST
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Chalov K. V. et al. Petroleum-containing residue processing via co-catalyzed pyrolysis // Fuel. 2017. Vol. 198. pp. 159-164.
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Chalov K. V., Lugovoy Y., Kosivtsov Y., Stepacheva A. A., Molchanov V., Smirnov I., Panfilov V., Sulman E. P. Petroleum-containing residue processing via co-catalyzed pyrolysis // Fuel. 2017. Vol. 198. pp. 159-164.
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RIS
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TY - JOUR
DO - 10.1016/j.fuel.2016.08.055
UR - https://doi.org/10.1016/j.fuel.2016.08.055
TI - Petroleum-containing residue processing via co-catalyzed pyrolysis
T2 - Fuel
AU - Chalov, Kirill V
AU - Lugovoy, Yury
AU - Kosivtsov, Yury
AU - Stepacheva, Antonina A
AU - Molchanov, Vladimir
AU - Smirnov, Iliya
AU - Panfilov, Viktor
AU - Sulman, E. P.
PY - 2017
DA - 2017/06/01
PB - Elsevier
SP - 159-164
VL - 198
SN - 0016-2361
SN - 1873-7153
ER -
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BibTex (up to 50 authors)
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@article{2017_Chalov,
author = {Kirill V Chalov and Yury Lugovoy and Yury Kosivtsov and Antonina A Stepacheva and Vladimir Molchanov and Iliya Smirnov and Viktor Panfilov and E. P. Sulman},
title = {Petroleum-containing residue processing via co-catalyzed pyrolysis},
journal = {Fuel},
year = {2017},
volume = {198},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.fuel.2016.08.055},
pages = {159--164},
doi = {10.1016/j.fuel.2016.08.055}
}