Open Access
Upgrading of chlorinated oils coming from pyrolysis of plastic waste
Publication type: Journal Article
Publication date: 2015-09-01
scimago Q1
wos Q1
SJR: 1.602
CiteScore: 17.0
Impact factor: 7.7
ISSN: 03783820, 18737188
General Chemical Engineering
Energy Engineering and Power Technology
Fuel Technology
Abstract
The objective of this paper is the upgrading of chlorinated oils coming from the pyrolysis of mixed plastic waste, in order to use them as fuel or feedstock for refineries. Two different samples of pyrolysis oils have been thermally and catalytically cracked in a 300 mL autoclave at 325 °C and the auto-generated pressure. Thermal cracking converts the plastic pyrolysis heavy oils into light liquid fractions which are only composed of alkanes and aromatics. These light fractions present a very low quantity of chlorine compared to the initial oils and resemble gasoline and diesel-like products. Besides, a gaseous fraction rich in methane and with very high heating value is also produced, together with a fuel-like viscous product which remains in the autoclave. The relative proportions of each of these three fractions depend on the nature of the initial oils. Red Mud has proved to be a dehydrochlorination and cracking catalyst, since it gives rise to higher quantity of gases and light liquid fractions with a very low chlorine content (
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46
Total citations:
46
Citations from 2024:
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(23.91%)
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GOST
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Lopez Urionabarrenechea A. et al. Upgrading of chlorinated oils coming from pyrolysis of plastic waste // Fuel Processing Technology. 2015. Vol. 137. pp. 229-239.
GOST all authors (up to 50)
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Lopez Urionabarrenechea A., de Marco I., Caballero B., Laresgoiti M., Adrados A. Upgrading of chlorinated oils coming from pyrolysis of plastic waste // Fuel Processing Technology. 2015. Vol. 137. pp. 229-239.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.fuproc.2015.04.015
UR - https://doi.org/10.1016/j.fuproc.2015.04.015
TI - Upgrading of chlorinated oils coming from pyrolysis of plastic waste
T2 - Fuel Processing Technology
AU - Lopez Urionabarrenechea, Alexander
AU - de Marco, Isabel
AU - Caballero, B.M
AU - Laresgoiti, M.F
AU - Adrados, A
PY - 2015
DA - 2015/09/01
PB - Elsevier
SP - 229-239
VL - 137
SN - 0378-3820
SN - 1873-7188
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Lopez Urionabarrenechea,
author = {Alexander Lopez Urionabarrenechea and Isabel de Marco and B.M Caballero and M.F Laresgoiti and A Adrados},
title = {Upgrading of chlorinated oils coming from pyrolysis of plastic waste},
journal = {Fuel Processing Technology},
year = {2015},
volume = {137},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.fuproc.2015.04.015},
pages = {229--239},
doi = {10.1016/j.fuproc.2015.04.015}
}