Open Access

Fuel Processing Technology

, volume 169 , pages 94-100

Dehydrogenation of polycyclic naphthenes on a Pt/C catalyst for hydrogen storage in liquid organic hydrogen carriers

Alexander N Kalenchuk ¹

Viktor I Bogdan ¹

Sergei F Dunaev ²

Leonid Kustov ^{1, 3, 4}

Hide authors affiliations Show authors affiliations: 4 affiliations

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Leninsky prospect 47, 119991, Russia |

Chemistry Department , Moscow State University , 119992, Moscow, Russia |

Chemistry Department, Moscow State University, 119992 Moscow, Russia |

⁴

National University of Science and Technology MISIS, Leninsky prosp. 4, Moscow, Russia |

Publication type: Journal Article

Publication date: 2018-01-01

Elsevier

Fuel Processing Technology

scimago Q1

wos Q1

SJR: 1.602

CiteScore: 17.0

Impact factor: 7.7

ISSN: 03783820, 18737188

DOI: 10.1016/j.fuproc.2017.09.023

Copy DOI

General Chemical Engineering

Energy Engineering and Power Technology

Fuel Technology

Abstract

Exhaustive hydrogenation of polyaromatic compounds with different extents of condensation (benzene, biphenyl, terphenyl) is studied. The reactions of catalytic dehydrogenation of the polycyclic naphthenic hydrocarbons (cyclohexane, bicyclohexyl, perhydroterphenyl) produced by hydrogenation of the aromatic substrates on a 3%Pt/Sibunit catalyst are explored in a flow setup in the temperature range 260–340 °С at the liquid hourly space velocity of 1 h − 1 . The directions of dehydrogenation of each of the studied substrates are studied in detail. Correlation dependences showing the effect of the structure of the molecules under study on their conversion in the dehydrogenation process are revealed. The influence of isomerization of steric and structural isomers on the kinetics of the entire process is established.

Found

1 citation

Eliseev O

87 publications, 736 citations, 3 reviews

h-index: 17

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Peoples' Friendship University of Russia

1 citation

Kononov Leonid

DSc in Chemistry

150 publications, 2 090 citations, 30 reviews

h-index: 25

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

1 citation

Turovtsev Vladimir

90 publications, 434 citations

h-index: 11

Tver State University

Research interests

Anharmonic oscillations

Internal rotation

Quantum Chemistry

Quantum mechanics of molecules

Spectroscopy

Statistical physics

The electronic structure of molecules

The quantum theory of atoms in molecules

Thermodynamics

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Cite this

GOST |

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GOST Copy

Kalenchuk A. N. et al. Dehydrogenation of polycyclic naphthenes on a Pt/C catalyst for hydrogen storage in liquid organic hydrogen carriers // Fuel Processing Technology. 2018. Vol. 169. pp. 94-100.

GOST all authors (up to 50) Copy

Kalenchuk A. N., Bogdan V. I., Dunaev S. F., Kustov L. Dehydrogenation of polycyclic naphthenes on a Pt/C catalyst for hydrogen storage in liquid organic hydrogen carriers // Fuel Processing Technology. 2018. Vol. 169. pp. 94-100.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.fuproc.2017.09.023

UR - https://doi.org/10.1016/j.fuproc.2017.09.023

TI - Dehydrogenation of polycyclic naphthenes on a Pt/C catalyst for hydrogen storage in liquid organic hydrogen carriers

T2 - Fuel Processing Technology

AU - Kalenchuk, Alexander N

AU - Bogdan, Viktor I

AU - Dunaev, Sergei F

AU - Kustov, Leonid

PY - 2018

DA - 2018/01/01

PB - Elsevier

SP - 94-100

VL - 169

SN - 0378-3820

SN - 1873-7188

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2018_Kalenchuk,

author = {Alexander N Kalenchuk and Viktor I Bogdan and Sergei F Dunaev and Leonid Kustov},

title = {Dehydrogenation of polycyclic naphthenes on a Pt/C catalyst for hydrogen storage in liquid organic hydrogen carriers},

journal = {Fuel Processing Technology},

year = {2018},

volume = {169},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.fuproc.2017.09.023},

pages = {94--100},

doi = {10.1016/j.fuproc.2017.09.023}

}

Publisher

Elsevier

Journal

Fuel Processing Technology

scimago Q1

wos Q1

SJR

1.602

CiteScore

17.0

Impact factor

7.7

ISSN

03783820 (Print)

18737188