Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species
Publication type: Journal Article
Publication date: 2004-04-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Sequential conversion of molecular oxygen into peroxo- and hydroperoxo-metal species involved in an effective O2-activation is verified for the TpiPr2Rh system by isolation and characterization of the intermediates. O2-treatment of the Rh(I) precursor, TpiPr2Rh(dppe) (1), in the presence of 3,5-diisopropylpyrazole (H-pziPr2) gives the κ2-peroxometal complex, TpiPr2(H-pziPr2)Rh(κ2-O2) (2), which is subsequently converted to the hydroperoxo complex, TpiPr2(H-pzH2)(pzH2)Rh–OOH (4), upon treatment with pyrazole (H-pzH2). The peroxo species 2 and 4 have been characterized by spectroscopic and crystallographic methods and it is revealed that, in the present N-rich coordination system, the basic peroxo ligands (O2, OOH) form hydrogen-bonding interactions with the proximal N- and NH-functional groups.
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Takahashi Y. et al. Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species // Inorganica Chimica Acta. 2004. Vol. 357. No. 6. pp. 1711-1724.
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Takahashi Y., Hashimoto M., Hikichi S., Moro-oka Y., Akita M. Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species // Inorganica Chimica Acta. 2004. Vol. 357. No. 6. pp. 1711-1724.
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TY - JOUR
DO - 10.1016/j.ica.2003.12.022
UR - https://doi.org/10.1016/j.ica.2003.12.022
TI - Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species
T2 - Inorganica Chimica Acta
AU - Takahashi, Yoshiaki
AU - Hashimoto, Mariko
AU - Hikichi, Shiro
AU - Moro-oka, Yoshihiko
AU - Akita, Munetaka
PY - 2004
DA - 2004/04/01
PB - Elsevier
SP - 1711-1724
IS - 6
VL - 357
SN - 0020-1693
SN - 1873-3255
ER -
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BibTex (up to 50 authors)
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@article{2004_Takahashi,
author = {Yoshiaki Takahashi and Mariko Hashimoto and Shiro Hikichi and Yoshihiko Moro-oka and Munetaka Akita},
title = {Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species},
journal = {Inorganica Chimica Acta},
year = {2004},
volume = {357},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.ica.2003.12.022},
number = {6},
pages = {1711--1724},
doi = {10.1016/j.ica.2003.12.022}
}
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MLA
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Takahashi, Yoshiaki, et al. “Oxygenation of a low valent rhodium complex, TpiPr2Rh(dppe): sequential conversion of molecular oxygen into peroxo and hydroperoxo complexes and characterization of the peroxo species.” Inorganica Chimica Acta, vol. 357, no. 6, Apr. 2004, pp. 1711-1724. https://doi.org/10.1016/j.ica.2003.12.022.