Inorganica Chimica Acta

, volume 427 , pages 168-172

Synthesis, structure, and luminescence of the “octahedral” cluster Cu4I4(rac-IsMePCH2PMeIs)2 (Is=2,4,6-(i-Pr)3C6H2)

Ethan W Emerson ¹

Matthew F Cain ¹

Matthew D Sanderson ¹

Christopher B Knarr ¹

David S Glueck ¹

John C Ahern ²

Howard E Patterson ²

Arnold L. Rheingold ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Department of Chemistry, Dartmouth College, 6128 Burke Laboratory, Hanover, NH 03755, United States |

Department of Chemistry, University of Maine, Orono, ME, 04469, United States. |

Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093, United States |

Publication type: Journal Article

Publication date: 2015-03-01

Elsevier

Inorganica Chimica Acta

scimago Q3

wos Q2

SJR: 0.393

CiteScore: 5.5

Impact factor: 3.2

ISSN: 00201693, 18733255

DOI: 10.1016/j.ica.2014.12.012

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Reaction of the bis(phosphine) rac-IsMePCH2PMeIs (Is = 2,4,6-(i-Pr)3C6H2) with 2 equiv. of CuI gave the complex Cu4I4(rac-IsMePCH2PMeIs)2 (1) as a mixture of two diastereomers. The crystal structure of 1·4CHCl3 showed it adopted a distorted “octahedral” geometry with a rectangular Cu4 plane, two asymmetrically bridging μ4-iodides, two μ2-iodides and two bis(phosphines) bridging two copper atoms. On UV excitation in the solid state, cluster 1 showed temperature-dependent emission from 3XLCT (halide-to-ligand charge transfer) and 3CC (Cu4I4 cluster-centered) excited states.

Found

4 citations

Karasik Andrey

DSc in Chemistry, professor, associate member of the Russian Academy of Sciences

224 publications, 2 625 citations

h-index: 26

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Luminescence

Phosphorus ligands

3 citations

Gerasimova Tatiana

PhD in Physics and Mathematics

115 publications, 1 752 citations

h-index: 21

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

3 citations

Strelnik Igor

🥼 🤝

PhD in Chemistry

60 publications, 820 citations, 5 reviews

h-index: 17

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

"Smart" materials

Coordination Chemistry

Inorganic Chemistry

Luminescent materials

Organic Chemistry

Organoelement chemistry

Organophosphorus chemistry

1 citation

Islamov Daut

PhD

168 publications, 1 572 citations

h-index: 20

Kazan Scientific Center of the Russian Academy of Sciences

Research interests

X-ray diffraction analysis

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Emerson E. W. et al. Synthesis, structure, and luminescence of the “octahedral” cluster Cu4I4(rac-IsMePCH2PMeIs)2 (Is=2,4,6-(i-Pr)3C6H2) // Inorganica Chimica Acta. 2015. Vol. 427. pp. 168-172.

GOST all authors (up to 50) Copy

Emerson E. W., Cain M. F., Sanderson M. D., Knarr C. B., Glueck D. S., Ahern J. C., Patterson H. E., Rheingold A. L. Synthesis, structure, and luminescence of the “octahedral” cluster Cu4I4(rac-IsMePCH2PMeIs)2 (Is=2,4,6-(i-Pr)3C6H2) // Inorganica Chimica Acta. 2015. Vol. 427. pp. 168-172.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.ica.2014.12.012

UR - https://doi.org/10.1016/j.ica.2014.12.012

TI - Synthesis, structure, and luminescence of the “octahedral” cluster Cu4I4(rac-IsMePCH2PMeIs)2 (Is=2,4,6-(i-Pr)3C6H2)

T2 - Inorganica Chimica Acta

AU - Emerson, Ethan W

AU - Cain, Matthew F

AU - Sanderson, Matthew D

AU - Knarr, Christopher B

AU - Glueck, David S

AU - Ahern, John C

AU - Patterson, Howard E

AU - Rheingold, Arnold L.

PY - 2015

DA - 2015/03/01

PB - Elsevier

SP - 168-172

VL - 427

SN - 0020-1693

SN - 1873-3255

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2015_Emerson,

author = {Ethan W Emerson and Matthew F Cain and Matthew D Sanderson and Christopher B Knarr and David S Glueck and John C Ahern and Howard E Patterson and Arnold L. Rheingold},

title = {Synthesis, structure, and luminescence of the “octahedral” cluster Cu4I4(rac-IsMePCH2PMeIs)2 (Is=2,4,6-(i-Pr)3C6H2)},

journal = {Inorganica Chimica Acta},

year = {2015},

volume = {427},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.ica.2014.12.012},

pages = {168--172},

doi = {10.1016/j.ica.2014.12.012}

}

Publisher

Elsevier

Journal

Inorganica Chimica Acta

scimago Q3

wos Q2

SJR

0.393

CiteScore

5.5

Impact factor

3.2

ISSN

00201693 (Print)

18733255 (Electronic)