Synthesis and structural characterization of low-valent group 14 metal complexes based on aminobisphenol ligands
1
Publication type: Journal Article
Publication date: 2017-05-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Aminobisphenol supported germylenes (1a–3a), stannylenes (1b–3b) and plumbylenes (1c–3c) were synthesized by reaction of Lappert’s tetrylenes, [(Me3Si)2N]2M (M = Ge, Sn, Pb), with corresponding aminobisphenols R1N(CH2C6H2(OH)(t-Bu)R2)2, 1–3 (1: R1 = Et, R2 = Me; 2: R1 = Et, R2 = t-Bu; 3: R1 = CH2(Py-2), R2 = t-Bu). X-ray diffraction analysis revealed different coordination mode for germylene 3a and stannylene 3b with additional nitrogen donor in the structure of the ligand. Germylene 1a was converted to the rhenium complex 1aa by the reaction with Re(CO)5Br.
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Zaitsev K. V. et al. Synthesis and structural characterization of low-valent group 14 metal complexes based on aminobisphenol ligands // Inorganica Chimica Acta. 2017. Vol. 461. pp. 213-220.
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Zaitsev K. V., Kuchuk E. A., Churakov A. V., Navasardyan M. A., Egorov M. P., Zaitseva G. S., Karlov S. S. Synthesis and structural characterization of low-valent group 14 metal complexes based on aminobisphenol ligands // Inorganica Chimica Acta. 2017. Vol. 461. pp. 213-220.
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TY - JOUR
DO - 10.1016/j.ica.2017.02.024
UR - https://linkinghub.elsevier.com/retrieve/pii/S002016931630665X
TI - Synthesis and structural characterization of low-valent group 14 metal complexes based on aminobisphenol ligands
T2 - Inorganica Chimica Acta
AU - Zaitsev, K V
AU - Kuchuk, Ekaterina A.
AU - Churakov, Andrei V.
AU - Navasardyan, Mger A.
AU - Egorov, Mikhail P.
AU - Zaitseva, Galina S.
AU - Karlov, Sergey S.
PY - 2017
DA - 2017/05/01
PB - Elsevier
SP - 213-220
VL - 461
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2017_Zaitsev,
author = {K V Zaitsev and Ekaterina A. Kuchuk and Andrei V. Churakov and Mger A. Navasardyan and Mikhail P. Egorov and Galina S. Zaitseva and Sergey S. Karlov},
title = {Synthesis and structural characterization of low-valent group 14 metal complexes based on aminobisphenol ligands},
journal = {Inorganica Chimica Acta},
year = {2017},
volume = {461},
publisher = {Elsevier},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S002016931630665X},
pages = {213--220},
doi = {10.1016/j.ica.2017.02.024}
}