Self-assembly and SMM properties of lanthanide cyanocobaltate chain complexes with terpyridine as blocking ligand
Publication type: Journal Article
Publication date: 2018-10-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract A series of novel isomorphic 1D-polymeric complexes {[Ln(terpy)(H2O)3][Co(CN)6]·5H2O}n (Ln = Tb, Dy, Er, Yb; terpy is 2,2';6',2“-terpyridine) was prepared and characterized. Compounds Dy, Er and Yb were found to exhibit properties of field-induced single-molecule magnets with the anisotropy barriers of 68 K, 8 K and 37 K, respectively. Erbium complex Er seems to represent the first known example of Er-based cyanide-bridged 3d-4f SMM, whereas Yb is the second Yb-based one. The effect of the geometry of the coordination environment as well as of ligands field symmetry on SMM behavior of Dy, Er and Yb compounds is discussed. Among the cyanocobaltate-bridged chain complexes, the Dy, Er, Yb are the first series formed by the entire set of heavy Kramers ions which were studied as SMMs.
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Petrosyants S. P. et al. Self-assembly and SMM properties of lanthanide cyanocobaltate chain complexes with terpyridine as blocking ligand // Inorganica Chimica Acta. 2018. Vol. 482. pp. 813-820.
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Petrosyants S. P., Ilyukhin A. B., Efimov N. N., Gavrikov A., Novotortsev V. M. Self-assembly and SMM properties of lanthanide cyanocobaltate chain complexes with terpyridine as blocking ligand // Inorganica Chimica Acta. 2018. Vol. 482. pp. 813-820.
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TY - JOUR
DO - 10.1016/j.ica.2018.07.029
UR - https://linkinghub.elsevier.com/retrieve/pii/S0020169318309265
TI - Self-assembly and SMM properties of lanthanide cyanocobaltate chain complexes with terpyridine as blocking ligand
T2 - Inorganica Chimica Acta
AU - Petrosyants, Svetlana P.
AU - Ilyukhin, Andrey B.
AU - Efimov, Nikolay N.
AU - Gavrikov, A
AU - Novotortsev, Vladimir M.
PY - 2018
DA - 2018/10/01
PB - Elsevier
SP - 813-820
VL - 482
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2018_Petrosyants,
author = {Svetlana P. Petrosyants and Andrey B. Ilyukhin and Nikolay N. Efimov and A Gavrikov and Vladimir M. Novotortsev},
title = {Self-assembly and SMM properties of lanthanide cyanocobaltate chain complexes with terpyridine as blocking ligand},
journal = {Inorganica Chimica Acta},
year = {2018},
volume = {482},
publisher = {Elsevier},
month = {oct},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0020169318309265},
pages = {813--820},
doi = {10.1016/j.ica.2018.07.029}
}
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