Synthesis and characterization of three-coordinated Tin(II) chalcogenide compounds from chlorostannylene supported by β-diketiminato ligand
Mingdong Zhong
1
,
Yi Ding
1
,
Da Jin
1
,
Xiaoli Ma
1
,
Yashuai Liu
1
,
Ben Yan
1
,
Ying Yang
2
,
Jiong Peng
1
,
Zhi Yang
3, 4
2
Publication type: Journal Article
Publication date: 2019-02-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The stable chlorostannylene(II) LSnCl 1 reacted with bases or salts (KOH, t-BuOK, Ph3CSLi or Li2S), respectively, which led to the formation of a variety three-coordinated tin(II) chalcogens (O or S) (compounds 2–5). Compounds 2 and 5 are bridged bimetallic organotins(II) supported by a bidentate β-diketiminato ligand. Furthermore, the catalytic activity of compounds 2–5 for hydroboration with benzaldehyde and acetophenone were investigated, respectively. In the X-ray analyses of all stannylene chalcogenide compounds, the pyramidalization on the tin center are useful to enhanced p-character of lone pair. All compounds were characterized by 1H NMR and 13C NMR spectroscopy, single crystal X-ray structural analysis and elemental analysis.
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12
Total citations:
12
Citations from 2025:
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(25%)
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Zhong M. et al. Synthesis and characterization of three-coordinated Tin(II) chalcogenide compounds from chlorostannylene supported by β-diketiminato ligand // Inorganica Chimica Acta. 2019. Vol. 486. pp. 669-674.
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Zhong M., Ding Y., Jin D., Ma X., Liu Y., Yan B., Yang Y., Peng J., Yang Z. Synthesis and characterization of three-coordinated Tin(II) chalcogenide compounds from chlorostannylene supported by β-diketiminato ligand // Inorganica Chimica Acta. 2019. Vol. 486. pp. 669-674.
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RIS
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TY - JOUR
DO - 10.1016/j.ica.2018.11.033
UR - https://doi.org/10.1016/j.ica.2018.11.033
TI - Synthesis and characterization of three-coordinated Tin(II) chalcogenide compounds from chlorostannylene supported by β-diketiminato ligand
T2 - Inorganica Chimica Acta
AU - Zhong, Mingdong
AU - Ding, Yi
AU - Jin, Da
AU - Ma, Xiaoli
AU - Liu, Yashuai
AU - Yan, Ben
AU - Yang, Ying
AU - Peng, Jiong
AU - Yang, Zhi
PY - 2019
DA - 2019/02/01
PB - Elsevier
SP - 669-674
VL - 486
SN - 0020-1693
SN - 1873-3255
ER -
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BibTex (up to 50 authors)
Copy
@article{2019_Zhong,
author = {Mingdong Zhong and Yi Ding and Da Jin and Xiaoli Ma and Yashuai Liu and Ben Yan and Ying Yang and Jiong Peng and Zhi Yang},
title = {Synthesis and characterization of three-coordinated Tin(II) chalcogenide compounds from chlorostannylene supported by β-diketiminato ligand},
journal = {Inorganica Chimica Acta},
year = {2019},
volume = {486},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.ica.2018.11.033},
pages = {669--674},
doi = {10.1016/j.ica.2018.11.033}
}