Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine
Andrey Yu Baranov
1
,
Mariana I. Rakhmanova
2, 3
,
Denis G. Samsonenko
2, 3
,
Irina Yu. Bagryanskaya
3, 5
,
Vladimir P. Fedin
2, 3
,
Publication type: Journal Article
Publication date: 2019-08-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Coordination abilities of tris[2-(2-pyridyl)ethyl]phosphine (L) toward Ag(I) and Au(I) have been surveyed. Its reaction with AgClO4, AgNO3 and AgOTf results in self-assembly of 1D coordination polymers (CPs) of [Ag(L)X]n type (X = ClO4, NO3, OTf), built up by conjugated twelve-membered [Ag ( N C C C P P C C C N ) Ag] cycles. The reaction of this phosphine with AgCl affords CP [Ag4Cl4(L)2]n, where in stepped cubane [Ag4Cl4] modules are bridged by “PyCH2CH2P” arms. Interaction of L with Au(tht)Cl produces linear [Au(L)Cl] complex, in which P-coordination is observed. CPs [Ag(L)ClO4]n and [Ag4Cl4(L)2]n at ambient temperature show pronounced excitation wavelength dependent photoluminescence originated by intraligand transitions.
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33
Total citations:
33
Citations from 2025:
9
(27.27%)
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Baranov A. Yu. et al. Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine // Inorganica Chimica Acta. 2019. Vol. 494. pp. 78-83.
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Baranov A. Yu., Rakhmanova M. I., Samsonenko D. G., Malysheva S. A., Belogorlova N. A., Bagryanskaya I. Y., Fedin V. P., Artem'ev A. V. Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine // Inorganica Chimica Acta. 2019. Vol. 494. pp. 78-83.
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TY - JOUR
DO - 10.1016/j.ica.2019.05.015
UR - https://doi.org/10.1016/j.ica.2019.05.015
TI - Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine
T2 - Inorganica Chimica Acta
AU - Baranov, Andrey Yu
AU - Rakhmanova, Mariana I.
AU - Samsonenko, Denis G.
AU - Malysheva, Svetlana A.
AU - Belogorlova, Nataliya A.
AU - Bagryanskaya, Irina Yu.
AU - Fedin, Vladimir P.
AU - Artem'ev, Alexander V.
PY - 2019
DA - 2019/08/01
PB - Elsevier
SP - 78-83
VL - 494
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2019_Baranov,
author = {Andrey Yu Baranov and Mariana I. Rakhmanova and Denis G. Samsonenko and Svetlana A. Malysheva and Nataliya A. Belogorlova and Irina Yu. Bagryanskaya and Vladimir P. Fedin and Alexander V. Artem'ev},
title = {Silver(I) and gold(I) complexes with tris[2-(2-pyridyl)ethyl]phosphine},
journal = {Inorganica Chimica Acta},
year = {2019},
volume = {494},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.ica.2019.05.015},
pages = {78--83},
doi = {10.1016/j.ica.2019.05.015}
}
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