Sulfonium closo-hydridodecaborate anions as active components of a potentiometric membrane sensor for lidocaine hydrochloride
Тип публикации: Journal Article
Дата публикации: 2021-01-01
scimago Q3
wos Q2
БС2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A method for the preparation of sulfonium derivatives of the closo-hydridodecaborate anion [B10H9SR2]– with exo-polyhedral alkyl groups (R = i-Pr, n-Pr, n-Bu, n-C8H17, n-C12H25, n-C18H37) has been developed. A procedure for the preparation of mono-S-substituted derivatives of the closo-hydridodecaborate anion by the interaction between the [B10H9SH]2– anion and secondary alkyl halides has been developed. This paper presents the results of studies on the use of the sulfonium derivative of the closo-hydridodecaborate anion [B10H9S(C18H37)2]– as the active component of a hybrid polymer membrane designed to create a potentiometric lidocaine-selective sensor. The optimal composition of the proposed membrane composition has been found. The electroanalytical characteristics of the manufactured potentiometric sensor have been determined; the detection limit of lidocaine has been found to be 3.5 • 10–8 M.
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Kubasov A. S. et al. Sulfonium closo-hydridodecaborate anions as active components of a potentiometric membrane sensor for lidocaine hydrochloride // Inorganica Chimica Acta. 2021. Vol. 514. p. 119992.
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Kubasov A. S., Turishev E. S., Kopytin A. V., Shpigun L. K., Zhizhin K. Y., Kuznetsov N. T. Sulfonium closo-hydridodecaborate anions as active components of a potentiometric membrane sensor for lidocaine hydrochloride // Inorganica Chimica Acta. 2021. Vol. 514. p. 119992.
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TY - JOUR
DO - 10.1016/j.ica.2020.119992
UR - https://doi.org/10.1016/j.ica.2020.119992
TI - Sulfonium closo-hydridodecaborate anions as active components of a potentiometric membrane sensor for lidocaine hydrochloride
T2 - Inorganica Chimica Acta
AU - Kubasov, Alexey S.
AU - Turishev, E S
AU - Kopytin, A V
AU - Shpigun, L K
AU - Zhizhin, Konstantin Yu.
AU - Kuznetsov, N. T.
PY - 2021
DA - 2021/01/01
PB - Elsevier
SP - 119992
VL - 514
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2021_Kubasov,
author = {Alexey S. Kubasov and E S Turishev and A V Kopytin and L K Shpigun and Konstantin Yu. Zhizhin and N. T. Kuznetsov},
title = {Sulfonium closo-hydridodecaborate anions as active components of a potentiometric membrane sensor for lidocaine hydrochloride},
journal = {Inorganica Chimica Acta},
year = {2021},
volume = {514},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.ica.2020.119992},
pages = {119992},
doi = {10.1016/j.ica.2020.119992}
}
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