Effects of structure on the carbon dioxide methanation performance of Co-based catalysts

Mesoporous Co/KIT-6 and Co/meso-SiO 2 catalysts were prepared via hydrogen reduction and were subsequently used in CO 2 catalytic hydrogenation to produce methane. The properties of these catalysts were investigated via low-angle X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) analysis, and transmission electron microscopy (TEM). The results indicate that the synthesized Co/KIT-6 and Co/meso-SiO 2 catalysts have mesoporous structures with well-dispersed Co species, as well as high CO 2 catalytic hydrogenation activities. The Co/KIT-6 catalyst has a large specific surface area (368.9 m 2  g −1 ) and a highly ordered bicontinuous mesoporous structure. This catalyst exhibits excellent CO 2 catalytic hydrogenation activity and methane product selectivity, which are both higher than those of the Co/meso-SiO 2 catalyst at high reaction temperatures. The CO 2 conversion and methane selectivity of the Co/KIT-6 catalyst at 280 °C are 48.9% and 100%, respectively. The high dispersion of the Co species and the large specific surface area of the prepared Co-based catalysts contribute to the high catalytic activities. In addition, the highly ordered, bicontinuous, mesoporous structure of the Co/KIT-6 catalyst improves the selectivity for the methane product.