International Journal of Hydrogen Energy

, volume 45 , issue 25 , pages 13625-13642

Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production

Vladislav Sadykov ¹

Dmitry Medvedev ²

A. Kolchugin ²

A. V. Fetisov ³

Ekaterina M. Sadovskaya ¹

Elena Filonova ⁴

Nikita F. Eremeev ⁵

Vladimir Goncharov ⁵

Alexey V. Krasnov ⁵

Pavel I. Skriabin ⁵

ALEXANDER SHMAKOV ^{1, 6}

Zakhar S. Vinokurov ⁵

A. Ishchenko ¹

Sergey V. Pikalov ³

Hide authors affiliations Show authors affiliations: 6 affiliations

Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia |

Ural Federal University, Mira str. 19, Yekaterinburg, 620002, Russia |

Institute of Metallurgy, UB RAS, Amundsena Str. 101, Yekaterinburg, 620137, Russia |

⁴

Ural Federal University, Mira str. 19, Yekaterinburg 620002, Russia. |

⁵

Boreskov Institute of Catalysis SB RAS, Pr. Akad. Lavrentieva 5, Novosibirsk, 630090, Russia |

⁶

Budker Institute of Nuclear Physics SB RAS, Pr. Akad. Lavrentieva 11, Novosibirsk, 630090, Russia |

Publication type: Journal Article

Publication date: 2020-05-01

Elsevier

International Journal of Hydrogen Energy

scimago Q1

wos Q1

SJR: 1.685

CiteScore: 13.3

Impact factor: 8.3

ISSN: 03603199, 18793487

DOI: 10.1016/j.ijhydene.2018.03.039

Copy DOI

Condensed Matter Physics

Energy Engineering and Power Technology

Fuel Technology

Renewable Energy, Sustainability and the Environment

Abstract

Novel methods were applied in this work to elucidate the structure evolution of Ln2-xCaxNiO4+δ oxides (Ln = La, Pr, Nd; x = 0, 0.3) and study their oxygen mobility. Relationship between cations state, structural, electrical, electrochemical and kinetic properties was revealed. In all doped materials the overall oxygen mobility characterized by Do declined by more than an order of magnitude due to decreasing the interstitial oxygen content and hampering cooperative mechanism of oxygen migration. For La nikelate additional slow diffusion channel appears with DO 5.4·10−14 cm2/s at 700 K. Correlation of electrochemical and oxygen transport properties was demonstrated. A high electrical conductivity (up to 120 S/cm at 700 K) in Ln1.7Ca0.3NiO4+δ (Ln = Pr, Nd) along with satisfactory oxygen mobility and electrochemical properties makes these materials promising for a wide row of electrochemical applications.

Found

9 citations

Filonova Elena

🤝

PhD in Chemistry, associate professor

80 publications, 1 334 citations, 469 reviews

h-index: 22

Ural Federal University

5 citations

Medvedev Dmitry

🤝

DSc in Chemistry

193 publications, 5 828 citations, 106 reviews

h-index: 44

Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences

Ural Federal University

1 citation

Suntsov A

🥼 🤝

PhD in Chemistry

84 publications, 706 citations, 22 reviews

h-index: 16

Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

Solid state chemistry

1 citation

Akhmadeev Albert

4 publications, 30 citations

h-index: 3

Institute of Rare Metals

1 citation

Tarutin Artem

33 publications, 848 citations, 3 reviews

h-index: 15

Institute of High Temperature Electrochemistry of the Ural Branch of the Russian Academy of Sciences

Ural Federal University

Research interests

Inorganic Chemistry

1 citation

Grobovoy Ivan

5 publications, 7 citations

h-index: 2

Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences

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GOST |

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GOST Copy

Sadykov V. et al. Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production // International Journal of Hydrogen Energy. 2020. Vol. 45. No. 25. pp. 13625-13642.

GOST all authors (up to 50) Copy

Sadykov V., Medvedev D., Kolchugin A., Fetisov A. V., Sadovskaya E. M., Filonova E., Eremeev N. F., Goncharov V., Krasnov A. V., Skriabin P. I., SHMAKOV A., Vinokurov Z. S., Ishchenko A., Pikalov S. V. Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production // International Journal of Hydrogen Energy. 2020. Vol. 45. No. 25. pp. 13625-13642.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.ijhydene.2018.03.039

UR - https://doi.org/10.1016/j.ijhydene.2018.03.039

TI - Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production

T2 - International Journal of Hydrogen Energy

AU - Sadykov, Vladislav

AU - Medvedev, Dmitry

AU - Kolchugin, A.

AU - Fetisov, A. V.

AU - Sadovskaya, Ekaterina M.

AU - Filonova, Elena

AU - Eremeev, Nikita F.

AU - Goncharov, Vladimir

AU - Krasnov, Alexey V.

AU - Skriabin, Pavel I.

AU - SHMAKOV, ALEXANDER

AU - Vinokurov, Zakhar S.

AU - Ishchenko, A.

AU - Pikalov, Sergey V.

PY - 2020

DA - 2020/05/01

PB - Elsevier

SP - 13625-13642

IS - 25

VL - 45

SN - 0360-3199

SN - 1879-3487

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2020_Sadykov,

author = {Vladislav Sadykov and Dmitry Medvedev and A. Kolchugin and A. V. Fetisov and Ekaterina M. Sadovskaya and Elena Filonova and Nikita F. Eremeev and Vladimir Goncharov and Alexey V. Krasnov and Pavel I. Skriabin and ALEXANDER SHMAKOV and Zakhar S. Vinokurov and A. Ishchenko and Sergey V. Pikalov},

title = {Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production},

journal = {International Journal of Hydrogen Energy},

year = {2020},

volume = {45},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/j.ijhydene.2018.03.039},

number = {25},

pages = {13625--13642},

doi = {10.1016/j.ijhydene.2018.03.039}

}

MLA

Cite this

MLA Copy

Sadykov, Vladislav, et al. “Transport properties of Ca-doped Ln2NiO4 for intermediate temperature solid oxide fuel cells cathodes and catalytic membranes for hydrogen production.” International Journal of Hydrogen Energy, vol. 45, no. 25, May. 2020, pp. 13625-13642. https://doi.org/10.1016/j.ijhydene.2018.03.039.

Publisher

Elsevier

Journal

International Journal of Hydrogen Energy

scimago Q1

wos Q1

SJR

1.685

CiteScore

13.3

Impact factor

8.3

ISSN

03603199 (Print, Electronic)

18793487

Profiles

Elena A Filonova