International Journal of Hydrogen Energy, volume 58, pages 470-478
Assessment of polybenzimidazole/MOF composite membranes for the improvement of high-temperature PEM fuel cell performance
Publication type: Journal Article
Publication date: 2024-03-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 7.2
ISSN: 03603199
Condensed Matter Physics
Energy Engineering and Power Technology
Fuel Technology
Renewable Energy, Sustainability and the Environment
Abstract
This study aims to determine the most effective utilization of ZIF-8 type metal-organic framework (MOF) doped polybenzimidazole (PBI) composite membrane in high-temperature polymer electrolyte membrane fuel cells (HT-PEMFC) and investigate how ZIF-8 filler affects performance. ZIF-8 particles were prepared by solvothermal method and added to the PBI polymer using a weight percentage varying from 1 to 5 %. XRD, BET, and TEM examined the prepared ZIF-8. Composite membrane properties were investigated by XRD, SEM analysis, proton conductivity measurements, acid doping, and acid stripping tests. The HT-PEMFC performances of the membranes were carried out using Hydrogen and dry air at 150–180. The highest performance was acquired with the composite ZIF8/PBI-2 membrane as 0.432 W/cm2 at 170 °C. The obtained result is explained by easier proton transfer over ZIF-8's enlarged tunnel network. This study proposes a promising strategy to use ZIF-8 to prepare a PBI composite membrane with excellent proton conductivity, acid doping, and low acid leaching for HT-PEMFC application. The current study's findings can support future research on PBI/MOF-based composite membranes for HT-PEMFC applications.
Top-30
Citations by journals
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Journal of Membrane Science
2 publications, 25%
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International Journal of Hydrogen Energy
2 publications, 25%
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Russian Chemical Reviews
1 publication, 12.5%
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ACS Sustainable Chemistry and Engineering
1 publication, 12.5%
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Journal of Energy Storage
1 publication, 12.5%
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Journal of Power Sources
1 publication, 12.5%
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Citations by publishers
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Elsevier
6 publications, 75%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 12.5%
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American Chemical Society (ACS)
1 publication, 12.5%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Devrim Y., Cakici D. M. Assessment of polybenzimidazole/MOF composite membranes for the improvement of high-temperature PEM fuel cell performance // International Journal of Hydrogen Energy. 2024. Vol. 58. pp. 470-478.
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Devrim Y., Cakici D. M. Assessment of polybenzimidazole/MOF composite membranes for the improvement of high-temperature PEM fuel cell performance // International Journal of Hydrogen Energy. 2024. Vol. 58. pp. 470-478.
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TY - JOUR
DO - 10.1016/j.ijhydene.2024.01.184
UR - https://doi.org/10.1016/j.ijhydene.2024.01.184
TI - Assessment of polybenzimidazole/MOF composite membranes for the improvement of high-temperature PEM fuel cell performance
T2 - International Journal of Hydrogen Energy
AU - Devrim, Yılser
AU - Cakici, Duygu Melek
PY - 2024
DA - 2024/03/01 00:00:00
PB - Elsevier
SP - 470-478
VL - 58
SN - 0360-3199
ER -
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@article{2024_Devrim,
author = {Yılser Devrim and Duygu Melek Cakici},
title = {Assessment of polybenzimidazole/MOF composite membranes for the improvement of high-temperature PEM fuel cell performance},
journal = {International Journal of Hydrogen Energy},
year = {2024},
volume = {58},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.ijhydene.2024.01.184},
pages = {470--478},
doi = {10.1016/j.ijhydene.2024.01.184}
}