Elsevier
Inorganic Chemistry Communication
,  volume 61 ,  pages 21-23

Synthesis of acyclic diaminocarbene palladium complex featuring triethoxysilane moiety

Valentin A Rassadin 1, 2, 3
, 
Anton A Yakimanskiy 1, 2, 3
, 
Evgeniy V Eliseenkov 1, 2, 3
, 
Vadim P Boyarskiy 1, 2, 3
1
 
Institute of Chemistry
2
 
3
 
Universitetskii pr. 26 198504 Saint Petersburg Russia | 
Publication type: Journal Article
Publication date: 2015-11-01
Elsevier
scimago Q1
wos Q1
SJR: 0.758
CiteScore: 6.7
Impact factor: 5.4
ISSN: 13877003, 18790259
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The first example of an acyclic diaminocarbene palladium complex, viz. cis-[PdCl2(CN(2,6-Me2C6H3)){C(NH(2,6-Me2C6H3)) = NH(CH2)3Si(OEt)3}], featuring the triethoxysilane moiety is described. The complex was generated from bis(o-xylylisocyanide)palladium dichloride and (3-aminopropyl)triethoxysilane under mild conditions and isolated in 88% yield. The target compound is stable at RT either in the solid state or in CDCl3 or CD3OD solutions within several months.
Found 
Found 

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GOST Copy
Rassadin V. A. et al. Synthesis of acyclic diaminocarbene palladium complex featuring triethoxysilane moiety // Inorganic Chemistry Communication. 2015. Vol. 61. pp. 21-23.
GOST all authors (up to 50) Copy
Rassadin V. A., Yakimanskiy A. A., Eliseenkov E. V., Boyarskiy V. P. Synthesis of acyclic diaminocarbene palladium complex featuring triethoxysilane moiety // Inorganic Chemistry Communication. 2015. Vol. 61. pp. 21-23.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.inoche.2015.08.008
UR - https://doi.org/10.1016/j.inoche.2015.08.008
TI - Synthesis of acyclic diaminocarbene palladium complex featuring triethoxysilane moiety
T2 - Inorganic Chemistry Communication
AU - Rassadin, Valentin A
AU - Yakimanskiy, Anton A
AU - Eliseenkov, Evgeniy V
AU - Boyarskiy, Vadim P
PY - 2015
DA - 2015/11/01
PB - Elsevier
SP - 21-23
VL - 61
SN - 1387-7003
SN - 1879-0259
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Rassadin,
author = {Valentin A Rassadin and Anton A Yakimanskiy and Evgeniy V Eliseenkov and Vadim P Boyarskiy},
title = {Synthesis of acyclic diaminocarbene palladium complex featuring triethoxysilane moiety},
journal = {Inorganic Chemistry Communication},
year = {2015},
volume = {61},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.inoche.2015.08.008},
pages = {21--23},
doi = {10.1016/j.inoche.2015.08.008}
}