volume 67 pages 1-5

Titanium complexes based on pyridine containing dialcohols: Effect of a ligand

Publication typeJournal Article
Publication date2016-05-01
scimago Q1
wos Q1
SJR0.758
CiteScore6.7
Impact factor5.4
ISSN13877003, 18790259
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract Substituted 2,6-bis(hydroxyalkyl)pyridines, H2L, 1–3 (2,6-Py(CH2(X)OH)(CH2(Y)OH), X = Y = cyclo-C6H10, 1; X = Y = 1-Ad, 2; X = CPh2, Y = CH2CPh2, 3), were used as ligands for the synthesis of titanium(IV) complexes, (i-PrO)2Ti(L), 1a–3a. On the contrary, application of related dialcohol based on 2,2′-bipyridine, H2L′, 5 (2,2′-bipy-6,6′-(CH2Ph2OH)2), resulted in titanyl complex, (L′)Ti O, 6. The molecular structure of 6 was investigated by X-ray analysis. Compounds 1a and 3a were tested as initiators in ring-opening polymerization of l -lactide and e-caprolactone showing moderate activity.
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Kuchuk E. A. et al. Titanium complexes based on pyridine containing dialcohols: Effect of a ligand // Inorganic Chemistry Communication. 2016. Vol. 67. pp. 1-5.
GOST all authors (up to 50) Copy
Kuchuk E. A., Mankaev B. N., Zaitsev K. V., Oprunenko Y. F., Churakov A. V., Zaitseva G. S., Karlov S. S. Titanium complexes based on pyridine containing dialcohols: Effect of a ligand // Inorganic Chemistry Communication. 2016. Vol. 67. pp. 1-5.
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RIS Copy
TY - JOUR
DO - 10.1016/j.inoche.2016.02.023
UR - https://linkinghub.elsevier.com/retrieve/pii/S1387700316300533
TI - Titanium complexes based on pyridine containing dialcohols: Effect of a ligand
T2 - Inorganic Chemistry Communication
AU - Kuchuk, Ekaterina A.
AU - Mankaev, Badma N.
AU - Zaitsev, K V
AU - Oprunenko, Yuri F.
AU - Churakov, Andrei V.
AU - Zaitseva, Galina S.
AU - Karlov, Sergey S.
PY - 2016
DA - 2016/05/01
PB - Elsevier
SP - 1-5
VL - 67
SN - 1387-7003
SN - 1879-0259
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Kuchuk,
author = {Ekaterina A. Kuchuk and Badma N. Mankaev and K V Zaitsev and Yuri F. Oprunenko and Andrei V. Churakov and Galina S. Zaitseva and Sergey S. Karlov},
title = {Titanium complexes based on pyridine containing dialcohols: Effect of a ligand},
journal = {Inorganic Chemistry Communication},
year = {2016},
volume = {67},
publisher = {Elsevier},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1387700316300533},
pages = {1--5},
doi = {10.1016/j.inoche.2016.02.023}
}