Kinetic analysis of the complete mechanochemical synthesis of a palladium(II) carbene complex
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q1
wos Q1
SJR: 0.758
CiteScore: 6.7
Impact factor: 5.4
ISSN: 13877003, 18790259
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Benzimidazoline-2-ylidene complexes of palladium(II) were synthesized mechanochemically in a vibratory ball mill. Complete syntheses began with preparation of benzimidiazolium halides from commercially available starting materials. These “greener chemistry” syntheses proceed in high yield and require minimal purification using environmentally benign solvents. Kinetic analysis shows that liquid assisted grinding impedes the production to benzimidazolium halides while enhancing the production of the palladium-carbene complex.
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GOST
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Allenbaugh R. J. et al. Kinetic analysis of the complete mechanochemical synthesis of a palladium(II) carbene complex // Inorganic Chemistry Communication. 2020. Vol. 111. p. 107622.
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Allenbaugh R. J., Zachary J. R., Underwood A. N., Bryson J. D., Williams J. R., Shaw A. Kinetic analysis of the complete mechanochemical synthesis of a palladium(II) carbene complex // Inorganic Chemistry Communication. 2020. Vol. 111. p. 107622.
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TY - JOUR
DO - 10.1016/j.inoche.2019.107622
UR - https://doi.org/10.1016/j.inoche.2019.107622
TI - Kinetic analysis of the complete mechanochemical synthesis of a palladium(II) carbene complex
T2 - Inorganic Chemistry Communication
AU - Allenbaugh, Rachel J
AU - Zachary, Jonathon R
AU - Underwood, A Nicole
AU - Bryson, J Dillion
AU - Williams, Joseph R
AU - Shaw, Angela
PY - 2020
DA - 2020/01/01
PB - Elsevier
SP - 107622
VL - 111
SN - 1387-7003
SN - 1879-0259
ER -
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BibTex (up to 50 authors)
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@article{2020_Allenbaugh,
author = {Rachel J Allenbaugh and Jonathon R Zachary and A Nicole Underwood and J Dillion Bryson and Joseph R Williams and Angela Shaw},
title = {Kinetic analysis of the complete mechanochemical synthesis of a palladium(II) carbene complex},
journal = {Inorganic Chemistry Communication},
year = {2020},
volume = {111},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.inoche.2019.107622},
pages = {107622},
doi = {10.1016/j.inoche.2019.107622}
}