Journal of Analytical and Applied Pyrolysis, volume 117, pages 214-219

Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides

Publication typeJournal Article
Publication date2016-01-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor6
ISSN01652370
Analytical Chemistry
Fuel Technology
Abstract
A reinterpretation of the spectroscopic data for the products of flash vacuum pyrolysis (FVP) of 8- and 9-membered polymethylenetetrazoles 1, 3, 5, and 7 with annelated benzene rings indicates that these are not cyanamides 2, 4, 6, and 8, but 9- and 10-membered cyclic carbodiimides 9, 10, 11, and 12. FVP of the corresponding tetrazolo[1,5-a]azocine and tetrazolo[1,5-a]azonine derivatives 13 and 17 was investigated by isolation of the products in cryogenic matrices and by matrix photolysis and found to yield 9- and 10-membered cyclic carbodiimides 14 and 18 as transient intermediates en route to indolo[2,3-b]quinoline 15 and dibenzo[b,f]naphthyridine 19.

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Wentrup C., Vosswinkel M. Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides // Journal of Analytical and Applied Pyrolysis. 2016. Vol. 117. pp. 214-219.
GOST all authors (up to 50) Copy
Wentrup C., Vosswinkel M. Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides // Journal of Analytical and Applied Pyrolysis. 2016. Vol. 117. pp. 214-219.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jaap.2015.11.013
UR - https://doi.org/10.1016/j.jaap.2015.11.013
TI - Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides
T2 - Journal of Analytical and Applied Pyrolysis
AU - Wentrup, Curt
AU - Vosswinkel, Michael
PY - 2016
DA - 2016/01/01 00:00:00
PB - Elsevier
SP - 214-219
VL - 117
SN - 0165-2370
ER -
BibTex
Cite this
BibTex Copy
@article{2016_Wentrup,
author = {Curt Wentrup and Michael Vosswinkel},
title = {Pyrolysis of annelated hexa- and heptamethylene-tetrazoles: Formation of 9- and 10-membered cyclic carbodiimides},
journal = {Journal of Analytical and Applied Pyrolysis},
year = {2016},
volume = {117},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.jaap.2015.11.013},
pages = {214--219},
doi = {10.1016/j.jaap.2015.11.013}
}
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