Synthesis and thermochemistry of new phase BaCe0.7Nd0.2In0.1O2.85
N.I. Matskevich
1
,
Mariya Yu Matskevich
1
,
Thomas M. Wolf
2
,
Anna N Bryzgalova
1
,
Tatyana I Chupakhina
3
,
Olga I Anyfrieva
1
2
Publication type: Journal Article
Publication date: 2013-11-01
scimago Q1
wos Q1
SJR: 1.192
CiteScore: 11.8
Impact factor: 6.3
ISSN: 09258388, 18734669
Materials Chemistry
Metals and Alloys
Mechanical Engineering
Mechanics of Materials
Abstract
The BaCe 0.7 Nd 0.2 In 0.1 O 2.85 phase has been prepared from BaCO 3 , CeO 2 , Nd 2 O 3 and In 2 O 3 . X-ray measurements have showed that BaCe 0.7 Nd 0.2 In 0.1 O 2.85 has an orthorhombic structure ( Pmcn space group). The standard formation enthalpy of BaCe 0.7 Nd 0.2 In 0.1 O 2.85 has been determined by solution calorimetry combining solution enthalpies of BaCe 0.7 Nd 0.2 In 0.1 O 2.85 , BaCl 2 + 0.7CeCl 3 + 0.2NdCl 3 + 0.1InCl 3 mixture in 1 M HCl with KI and literature data. We determined the thermodynamic stability of Nd(In)-doped barium cerate with respect to mixtures of binary oxides. On the basis of the data we established that above-mentioned mixed oxide is thermodynamically stable with respect to their decomposition into binary oxides at room temperatures. We also established that BaCe 0.7 Nd 0.2 In 0.1 O 2.85 is thermodynamically favored than BaCe 0.8 Nd 0.2 O 2.9 .
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Matskevich N. et al. Synthesis and thermochemistry of new phase BaCe0.7Nd0.2In0.1O2.85 // Journal of Alloys and Compounds. 2013. Vol. 577. pp. 148-151.
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Matskevich N., Matskevich M. Yu., Wolf T. M., Bryzgalova A. N., Chupakhina T. I., Anyfrieva O. I. Synthesis and thermochemistry of new phase BaCe0.7Nd0.2In0.1O2.85 // Journal of Alloys and Compounds. 2013. Vol. 577. pp. 148-151.
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RIS
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TY - JOUR
DO - 10.1016/j.jallcom.2013.04.194
UR - https://doi.org/10.1016/j.jallcom.2013.04.194
TI - Synthesis and thermochemistry of new phase BaCe0.7Nd0.2In0.1O2.85
T2 - Journal of Alloys and Compounds
AU - Matskevich, N.I.
AU - Matskevich, Mariya Yu
AU - Wolf, Thomas M.
AU - Bryzgalova, Anna N
AU - Chupakhina, Tatyana I
AU - Anyfrieva, Olga I
PY - 2013
DA - 2013/11/01
PB - Elsevier
SP - 148-151
VL - 577
SN - 0925-8388
SN - 1873-4669
ER -
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@article{2013_Matskevich,
author = {N.I. Matskevich and Mariya Yu Matskevich and Thomas M. Wolf and Anna N Bryzgalova and Tatyana I Chupakhina and Olga I Anyfrieva},
title = {Synthesis and thermochemistry of new phase BaCe0.7Nd0.2In0.1O2.85},
journal = {Journal of Alloys and Compounds},
year = {2013},
volume = {577},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.jallcom.2013.04.194},
pages = {148--151},
doi = {10.1016/j.jallcom.2013.04.194}
}