Isomorphous substitutions and conductivity in molybdates Nd 5−x Ln x Mo 3 O 16+y ( y ∼0.5), where Ln = La, Ce, Pr
2
Department of Chemistry and Geology, Minnesota State University, 241 Ford Hall, Mankato, MN 56001, USA
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Publication type: Journal Article
Publication date: 2016-11-01
scimago Q1
wos Q1
SJR: 1.192
CiteScore: 11.8
Impact factor: 6.3
ISSN: 09258388, 18734669
Materials Chemistry
Metals and Alloys
Mechanical Engineering
Mechanics of Materials
Abstract
Neodymium substitution in rare earth elements (REE) was studied in the systems Nd 5−x Ln x Mo 3 O 16+y , where Ln = La, Ce, Pr with y ∼0.5 by means of X-ray powder diffraction (including the Rietveld algorithm), scanning electron microscopy (SEM) and by measurements of the electrical conductivity. At x values of 0.5, 0.3, and 5.0 the mixtures of REE oxides with MoO 3 transform to single-phase solid solutions with fluorite-related structure and doubled fluorite unit cell parameters as a result of solid state reactions occurring at 1050 °C. In the systems with La and Pr the unit cell parameter of solid solutions increases with x . While in the system with Ce this parameters decrease. Conductivity of ceramic solid electrolytes increases up to 17 times compared with the unmodified Nd 5 Mo 3 O 16+y .
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Get’man E. I. et al. Isomorphous substitutions and conductivity in molybdates Nd 5−x Ln x Mo 3 O 16+y ( y ∼0.5), where Ln = La, Ce, Pr // Journal of Alloys and Compounds. 2016. Vol. 686. pp. 90-94.
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Get’man E. I., Chebyshev K. A., Pasechnik L. V., Ardanova L. I., Selikova N. I., Radio S. V. Isomorphous substitutions and conductivity in molybdates Nd 5−x Ln x Mo 3 O 16+y ( y ∼0.5), where Ln = La, Ce, Pr // Journal of Alloys and Compounds. 2016. Vol. 686. pp. 90-94.
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TY - JOUR
DO - 10.1016/j.jallcom.2016.06.005
UR - https://doi.org/10.1016/j.jallcom.2016.06.005
TI - Isomorphous substitutions and conductivity in molybdates Nd 5−x Ln x Mo 3 O 16+y ( y ∼0.5), where Ln = La, Ce, Pr
T2 - Journal of Alloys and Compounds
AU - Get’man, E. I.
AU - Chebyshev, Konstantin A
AU - Pasechnik, L V
AU - Ardanova, L. I.
AU - Selikova, Natalia I
AU - Radio, S. V.
PY - 2016
DA - 2016/11/01
PB - Elsevier
SP - 90-94
VL - 686
SN - 0925-8388
SN - 1873-4669
ER -
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@article{2016_Get’man,
author = {E. I. Get’man and Konstantin A Chebyshev and L V Pasechnik and L. I. Ardanova and Natalia I Selikova and S. V. Radio},
title = {Isomorphous substitutions and conductivity in molybdates Nd 5−x Ln x Mo 3 O 16+y ( y ∼0.5), where Ln = La, Ce, Pr},
journal = {Journal of Alloys and Compounds},
year = {2016},
volume = {686},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.jallcom.2016.06.005},
pages = {90--94},
doi = {10.1016/j.jallcom.2016.06.005}
}
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