Journal of Alloys and Compounds, volume 767, pages 899-904

Li+ transport channel size governing Li+ migration in garnet-based all-solid-state lithium batteries

Yanhua Zhang ¹

Dongwei Hu ¹

Jiadong Deng ²

Fei Chen ³

Qiang Shen ³

Aikui Li ⁴

Jian Zhang ³

Shijie Dong ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

Hubei Provincial Key Laboratory of Green Materials for Light Industry Hubei University of Technology Wuhan 430068 China |

School of Automotive Engineering,Wuhan University of Technology,Wuhan 430070, China) |

State Key Lab of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China) |

⁴

Wuhan NARI Limited Company of State Grid Electric Power Research Institute, Wuhan 430070, China |

Publication type: Journal Article

Publication date: 2018-10-01

Elsevier

Journal: Journal of Alloys and Compounds

Quartile SCImago

Quartile WOS

Impact factor: 6.2

ISSN: 09258388

DOI: 10.1016/j.jallcom.2018.07.174

Copy DOI

Materials Chemistry

Metals and Alloys

Mechanical Engineering

Mechanics of Materials

Abstract

Li+ transport channel size of garnet-type Li7La3Z2O12 (LLZO) solid electrolytes is continuously regulated to study its governing of Li+ migration in application of all-solid-state batteries. Results show that the Li+ migration activation energy decrease with the decrease of Li+ transport channel size and then increase with further decrease of Li+ transport channel size. With Li+ transport channel size of 12.954 A, the Li+ migration activation energy reaches minimum of 0.28 eV. The cyclic voltammogram of Au/Li7La3-XCaXZr2-YTaYO12/Li cells show that, with Li+ transport channel size of 12.954 A, the redox peaks is at ±0.23 V, which is more symmetrical and closer to 0 V compared to both larger and smaller Li+ transport channel size of 12.961 A (0.38 V and −0.32 V) and 12.935 A (0.50 V and −0.40 V). This suggests that LLZO with Li+ transport channel size of 12.954 A has better charge-discharge reversibility of lithium deposition and dissolution and less energy consumption when used as solid electrolyte in all-solid-state lithium batteries.

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Citations by publishers

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Elsevier	Elsevier, 13, 46.43% Elsevier 13 publications, 46.43%
Springer Nature	Springer Nature, 4, 14.29% Springer Nature 4 publications, 14.29%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 10.71% Royal Society of Chemistry (RSC) 3 publications, 10.71%
Wiley	Wiley, 2, 7.14% Wiley 2 publications, 7.14%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 7.14% American Chemical Society (ACS) 2 publications, 7.14%
Tsinghua University Press	Tsinghua University Press, 1, 3.57% Tsinghua University Press 1 publication, 3.57%
Taylor & Francis	Taylor & Francis, 1, 3.57% Taylor & Francis 1 publication, 3.57%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.57% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.57%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.57% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.57%
	2 4 6 8 10 12 14

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Zhang Y. et al. Li+ transport channel size governing Li+ migration in garnet-based all-solid-state lithium batteries // Journal of Alloys and Compounds. 2018. Vol. 767. pp. 899-904.

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Zhang Y., Hu D., Deng J., Chen F., Shen Q., Li A., Zhang J., Dong S. Li+ transport channel size governing Li+ migration in garnet-based all-solid-state lithium batteries // Journal of Alloys and Compounds. 2018. Vol. 767. pp. 899-904.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.jallcom.2018.07.174

UR - https://doi.org/10.1016/j.jallcom.2018.07.174

TI - Li+ transport channel size governing Li+ migration in garnet-based all-solid-state lithium batteries

T2 - Journal of Alloys and Compounds

AU - Zhang, Yanhua

AU - Hu, Dongwei

AU - Deng, Jiadong

AU - Chen, Fei

AU - Shen, Qiang

AU - Li, Aikui

AU - Zhang, Jian

AU - Dong, Shijie

PY - 2018

DA - 2018/10/01 00:00:00

PB - Elsevier

SP - 899-904

VL - 767

SN - 0925-8388

ER -

BibTex

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BibTex Copy

@article{2018_Zhang,

author = {Yanhua Zhang and Dongwei Hu and Jiadong Deng and Fei Chen and Qiang Shen and Aikui Li and Jian Zhang and Shijie Dong},

title = {Li+ transport channel size governing Li+ migration in garnet-based all-solid-state lithium batteries},

journal = {Journal of Alloys and Compounds},

year = {2018},

volume = {767},

publisher = {Elsevier},

month = {oct},

url = {https://doi.org/10.1016/j.jallcom.2018.07.174},

pages = {899--904},

doi = {10.1016/j.jallcom.2018.07.174}

}

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Publisher

Elsevier

Journal

Journal of Alloys and Compounds

Quartile SCImago

Quartile WOS

Impact factor

6.2

ISSN

09258388 (Print)