Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units
V. V. Atuchin
1
,
Bair G. Bazarov
3
,
Olga D Chimitova
4
,
A. A. Krylov
5
,
Eugene A Maximovskiy
6
,
Alexey M. Pugachev
8
,
N.V. Surovtsev
8
,
Jibzema Bazarova
4
,
Yuriy Denisenko
9
,
T.A. Gavrilova
10
Publication type: Journal Article
Publication date: 2019-05-01
scimago Q1
wos Q1
SJR: 1.192
CiteScore: 11.8
Impact factor: 6.3
ISSN: 09258388, 18734669
Materials Chemistry
Metals and Alloys
Mechanical Engineering
Mechanics of Materials
Abstract
RbEu(MoO4)2 is synthesized by the two-step solid state reaction method. The crystal structure of RbEu(MoO4)2 is defined by Rietveld analysis in space group Pbcn with cell parameters a = 5.13502(5), b = 18.8581(2) and c = 8.12849(7) A, V = 787.13(1) A3, Z = 4 (RB = 0.86%). This molybdate possesses its phase transition at 817 K and melts at 1250 K. The Raman spectra were measured with the excitation at λ = 1064 and 514.5 nm. The photoluminescence spectrum is evaluated under the excitation at 514.5 nm. The absolute domination of hypersensitive 5D0→7F2 transition is observed. The ultranarrow 5D0→7F0 transition in RbEu(MoO4)2 is positioned at 580.2 nm being 0.2 nm blue shifted, with respect to that in Eu2(MoO4)3.
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Atuchin V. V. et al. Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units // Journal of Alloys and Compounds. 2019. Vol. 785. pp. 692-697.
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Atuchin V. V., Aleksandrovsky A., Bazarov B. G., Chimitova O. D., Krylov A. A., Maximovskiy E. A., Molokeev M. S., Oreshonkov A. S., Pugachev A. M., Surovtsev N., Bazarova J., Denisenko Y., Gavrilova T. Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units // Journal of Alloys and Compounds. 2019. Vol. 785. pp. 692-697.
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TY - JOUR
DO - 10.1016/j.jallcom.2019.01.013
UR - https://linkinghub.elsevier.com/retrieve/pii/S0925838819300131
TI - Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units
T2 - Journal of Alloys and Compounds
AU - Atuchin, V. V.
AU - Aleksandrovsky, Aleksandr
AU - Bazarov, Bair G.
AU - Chimitova, Olga D
AU - Krylov, A. A.
AU - Maximovskiy, Eugene A
AU - Molokeev, Maxim S.
AU - Oreshonkov, Aleksandr S.
AU - Pugachev, Alexey M.
AU - Surovtsev, N.V.
AU - Bazarova, Jibzema
AU - Denisenko, Yuriy
AU - Gavrilova, T.A.
PY - 2019
DA - 2019/05/01
PB - Elsevier
SP - 692-697
VL - 785
SN - 0925-8388
SN - 1873-4669
ER -
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@article{2019_Atuchin,
author = {V. V. Atuchin and Aleksandr Aleksandrovsky and Bair G. Bazarov and Olga D Chimitova and A. A. Krylov and Eugene A Maximovskiy and Maxim S. Molokeev and Aleksandr S. Oreshonkov and Alexey M. Pugachev and N.V. Surovtsev and Jibzema Bazarova and Yuriy Denisenko and T.A. Gavrilova},
title = {Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units},
journal = {Journal of Alloys and Compounds},
year = {2019},
volume = {785},
publisher = {Elsevier},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0925838819300131},
pages = {692--697},
doi = {10.1016/j.jallcom.2019.01.013}
}