Journal of Alloys and Compounds, volume 941, pages 168857
Effect of boron-based glass additives on the ionic conductivity of Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte
Jingrui Kang
1
,
Xu Guo
1
,
Rui Gu
1
,
Yi Tang
1
,
Haiguang Hao
1
,
Yu Liu
1
,
Li Jin
1
,
Xiaoyong Wei
1
Publication type: Journal Article
Publication date: 2023-04-01
Journal:
Journal of Alloys and Compounds
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 6.2
ISSN: 09258388
Materials Chemistry
Metals and Alloys
Mechanical Engineering
Mechanics of Materials
Abstract
Li1.3Al0.3Ti1.7(PO4)3 (LATP) is a promising candidate as the solid electrolyte in energy storage devices. For practical considerations, the most common ways to ameliorate the low density and high ionic resistance of LATP are usually to use glass additives. In this work, the boron-based (B2O3, B2O3-SiO2-PbO (BSP), and B2O3-SiO2-K2O-Al2O3 (BSKA)) glass are added into LATP by solid method. As the results, the main diffraction peaks of all prepared samples maintain the NASICON-type with the R-3c space group. Meanwhile, the symmetric stretching vibrations of O-P-O bands is redshifted with the addition of boron-based glass, which plays a positive role in bulk conductivity. Additionally, the introduction of boron-based glass additives is effective to increase the grain sizes of the LATP samples. The relative density of the sample is obtained from 93.37% to 95.42%. Furthermore, the total conductivities of 1.33 × 10−4, 1.37 × 10−4, 1.97 × 10−4 S cm−1 are obtained in ceramic samples after B2O3, BSP and BSKA glass additives adding, respectively. The activation energy shows a reduction of 5.26% to 0.36 eV after BSP and BSKA glass adding. Satisfactorily, B2O3, BSP and BSKA glass have a certain influence on the conductivity, and bear a more favorable argument for the regulation of the morphology and density in the future.
Top-30
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Citations by publishers
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6
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Elsevier
6 publications, 54.55%
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2 publications, 18.18%
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1 publication, 9.09%
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1 publication, 9.09%
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Springer Nature
1 publication, 9.09%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kang J. et al. Effect of boron-based glass additives on the ionic conductivity of Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte // Journal of Alloys and Compounds. 2023. Vol. 941. p. 168857.
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Kang J., Guo X., Gu R., Tang Y., Hao H., Liu Yu., Jin L., Wei X. Effect of boron-based glass additives on the ionic conductivity of Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte // Journal of Alloys and Compounds. 2023. Vol. 941. p. 168857.
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TY - JOUR
DO - 10.1016/j.jallcom.2023.168857
UR - https://doi.org/10.1016/j.jallcom.2023.168857
TI - Effect of boron-based glass additives on the ionic conductivity of Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte
T2 - Journal of Alloys and Compounds
AU - Kang, Jingrui
AU - Guo, Xu
AU - Gu, Rui
AU - Tang, Yi
AU - Hao, Haiguang
AU - Liu, Yu
AU - Jin, Li
AU - Wei, Xiaoyong
PY - 2023
DA - 2023/04/01 00:00:00
PB - Elsevier
SP - 168857
VL - 941
SN - 0925-8388
ER -
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@article{2023_Kang,
author = {Jingrui Kang and Xu Guo and Rui Gu and Yi Tang and Haiguang Hao and Yu Liu and Li Jin and Xiaoyong Wei},
title = {Effect of boron-based glass additives on the ionic conductivity of Li1.3Al0.3Ti1.7(PO4)3 solid electrolyte},
journal = {Journal of Alloys and Compounds},
year = {2023},
volume = {941},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.jallcom.2023.168857},
pages = {168857},
doi = {10.1016/j.jallcom.2023.168857}
}
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