Direct conversion of cellulose and lignocellulosic biomass into chemicals and biofuel with metal chloride catalysts
Тип публикации: Journal Article
Дата публикации: 2012-04-01
scimago Q1
wos Q1
БС1
SJR: 1.558
CiteScore: 10.9
Impact factor: 6.5
ISSN: 00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Краткое описание
Direct transformation of cellulose and sugarcane bagasse into 5-hydroxymethylfurfural (HMF) was carried out using single or combined metal chloride catalysts in DMA–LiCl solvent under microwave-assisted heating. Among several metal chloride catalysts studied, Zr(O)Cl2/CrCl3 combined catalyst was most effective enabling 57% HMF from cellulose fiber. Zr(O)Cl2/CrCl3 catalyst was also effective for the conversion of sugarcane bagasse to HMF and 5-ethoxymethyl-2-furfural (EMF), a promising biofuel. This report discloses one-pot synthesis of EMF from sugarcane bagasse for the first time and also reveals the maximum HMF yield known so far from sugarcane bagasse. Thus, the current catalytic system based on cheap and readily abundant zirconium and chromium salts presents an efficient method for EMF and HMF synthesis from inexpensive lignocellulosic biomass.
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ГОСТ
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Dutta S. et al. Direct conversion of cellulose and lignocellulosic biomass into chemicals and biofuel with metal chloride catalysts // Journal of Catalysis. 2012. Vol. 288. pp. 8-15.
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Dutta S., De S., Alam M. I., Abu-Omar M. M., Saha B. Direct conversion of cellulose and lignocellulosic biomass into chemicals and biofuel with metal chloride catalysts // Journal of Catalysis. 2012. Vol. 288. pp. 8-15.
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TY - JOUR
DO - 10.1016/j.jcat.2011.12.017
UR - https://doi.org/10.1016/j.jcat.2011.12.017
TI - Direct conversion of cellulose and lignocellulosic biomass into chemicals and biofuel with metal chloride catalysts
T2 - Journal of Catalysis
AU - Dutta, Saikat
AU - De, S
AU - Alam, Md. Imteyaz
AU - Abu-Omar, Mahdi M.
AU - Saha, B
PY - 2012
DA - 2012/04/01
PB - Elsevier
SP - 8-15
VL - 288
SN - 0021-9517
SN - 1090-2694
ER -
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BibTex (до 50 авторов)
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@article{2012_Dutta,
author = {Saikat Dutta and S De and Md. Imteyaz Alam and Mahdi M. Abu-Omar and B Saha},
title = {Direct conversion of cellulose and lignocellulosic biomass into chemicals and biofuel with metal chloride catalysts},
journal = {Journal of Catalysis},
year = {2012},
volume = {288},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.jcat.2011.12.017},
pages = {8--15},
doi = {10.1016/j.jcat.2011.12.017}
}
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