Journal of Energy Chemistry, volume 45, pages 7-17

Towards high-performance lithium metal anodes via the modification of solid electrolyte interphases

Zhen Hou 1
Jiaolong Zhang 2
Wenhui Wang 3
Qianwen Chen 1
Baohua Li 2
Chaolin Chao-Lin Li 3
Publication typeJournal Article
Publication date2020-06-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor13.1
ISSN20954956
Electrochemistry
Energy Engineering and Power Technology
Fuel Technology
Energy (miscellaneous)
Abstract
Li metal has been regarded as one of the most promising anodes for high-energy-density storage systems due to its high theoretical capacity and lowest electrochemical potential. Unfortunately, an unstable and non-uniform solid electrolyte interphase (SEI) deriving from the spontaneous reaction between Li metal anode and electrolyte causes uneven Li deposition, resulting in the growth of Li dendrites and low Coulombic efficiency, which have greatly hindered the practical application of Li metal batteries. Thus, the construction of a stable SEI is an effective approach to suppress the growth of Li dendrites and enhance the electrochemical performances of Li metal anode. In this review, we firstly introduce the formation process of inferior SEI of Li metal anode and the corresponding challenges caused by the unstable SEI. Next, recent progresses to modify SEI layer through the regulation of electrolyte compositions and ex-situ protective coating are summarized. Finally, the remained issues, challenges, and perspectives are also proposed on the basis of current research status and progress.

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GOST Copy
Hou Z. et al. Towards high-performance lithium metal anodes via the modification of solid electrolyte interphases // Journal of Energy Chemistry. 2020. Vol. 45. pp. 7-17.
GOST all authors (up to 50) Copy
Hou Z., Zhang J., Wang W., Chen Q., Li B., Chao-Lin Li C. Towards high-performance lithium metal anodes via the modification of solid electrolyte interphases // Journal of Energy Chemistry. 2020. Vol. 45. pp. 7-17.
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RIS Copy
TY - JOUR
DO - 10.1016/j.jechem.2019.09.028
UR - https://doi.org/10.1016/j.jechem.2019.09.028
TI - Towards high-performance lithium metal anodes via the modification of solid electrolyte interphases
T2 - Journal of Energy Chemistry
AU - Hou, Zhen
AU - Zhang, Jiaolong
AU - Wang, Wenhui
AU - Chen, Qianwen
AU - Li, Baohua
AU - Chao-Lin Li, Chaolin
PY - 2020
DA - 2020/06/01 00:00:00
PB - Elsevier
SP - 7-17
VL - 45
SN - 2095-4956
ER -
BibTex
Cite this
BibTex Copy
@article{2020_Hou,
author = {Zhen Hou and Jiaolong Zhang and Wenhui Wang and Qianwen Chen and Baohua Li and Chaolin Chao-Lin Li},
title = {Towards high-performance lithium metal anodes via the modification of solid electrolyte interphases},
journal = {Journal of Energy Chemistry},
year = {2020},
volume = {45},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jechem.2019.09.028},
pages = {7--17},
doi = {10.1016/j.jechem.2019.09.028}
}
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