Journal of Energy Chemistry, volume 64, pages 62-84

Advances and prospects of PVDF based polymer electrolytes

Publication typeJournal Article
Publication date2022-01-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor13.1
ISSN20954956
Electrochemistry
Energy Engineering and Power Technology
Fuel Technology
Energy (miscellaneous)
Abstract
PVDF solid electrolytes with excellent electrochemical stability, thermal stability and mechanical properties are promising to replace liquid electrolyte using in high performance and security solid lithium batteries. Exploring highly foldable batteries with no safety hazard is a crucial task for the realization of portable, wearable, and implantable electric devices. Given these concerns, developing solid-state batteries is one of the most promising routes to achieve this aspiration. Because of the excellent flexibility and processability, polyvinylidene fluoride (PVDF) based electrolytes possess great potential to pack high energy density flexible batteries, however, suffers the various intrinsic shortcomings such as inferior ionic conductivity, a high degree of crystallinity, and lack of reactive groups. Clearing the progress of the present state and concluding the specific challenges faced by PVDF based electrolytes will help to develop PVDF based polymer batteries. In this review, we summarize the recent progress of gel polymer electrolytes and all solid polymer electrolytes based on PVDF. The ion transport mechanisms and preparation methods of PVDF based electrolytes are briefly introduced. Meanwhile, the current design principle and properties of electrolytes are highlighted and systematically discussed. Some peculiar modified strategies performed in lithium–sulfur batteries and lithium–oxygen batteries are also included. Finally, this review describes the challenges and prospects of some solid-state electrolytes to provide strategies for manufacturing high-performance PVDF electrolytes aimed at practical application with flexible requirements.

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GOST |
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GOST Copy
Wu Y. et al. Advances and prospects of PVDF based polymer electrolytes // Journal of Energy Chemistry. 2022. Vol. 64. pp. 62-84.
GOST all authors (up to 50) Copy
Wu Y., Li Yu., Li Yu., Wang Y., Wang Y., Liu Q., Liu Q., Chen Q., Chen M. Advances and prospects of PVDF based polymer electrolytes // Journal of Energy Chemistry. 2022. Vol. 64. pp. 62-84.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jechem.2021.04.007
UR - https://doi.org/10.1016/j.jechem.2021.04.007
TI - Advances and prospects of PVDF based polymer electrolytes
T2 - Journal of Energy Chemistry
AU - Wu, Yixin
AU - Li, Yu
AU - Wang, Yang
AU - Liu, Qian
AU - Li, Yu
AU - Wang, Yang
AU - Liu, Qian
AU - Chen, Qingguo
AU - Chen, Minghua
PY - 2022
DA - 2022/01/01 00:00:00
PB - Elsevier
SP - 62-84
VL - 64
SN - 2095-4956
ER -
BibTex
Cite this
BibTex Copy
@article{2022_Wu,
author = {Yixin Wu and Yu Li and Yang Wang and Qian Liu and Yu Li and Yang Wang and Qian Liu and Qingguo Chen and Minghua Chen},
title = {Advances and prospects of PVDF based polymer electrolytes},
journal = {Journal of Energy Chemistry},
year = {2022},
volume = {64},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.jechem.2021.04.007},
pages = {62--84},
doi = {10.1016/j.jechem.2021.04.007}
}
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