Journal of Energy Chemistry, volume 75, pages 504-511
The interphasial degradation of 4.2 V-class poly(ethylene oxide)-based solid batteries beyond electrochemical voltage limit
Renzhi Huang
1
,
Da-Xin Yang
2
,
Fenglin Zhang
1
,
Wei Jiang
3
,
Canfu Zhang
1
,
Pengfei Yan
2
,
Min Ling
3
,
Huilin Pan
4
Publication type: Journal Article
Publication date: 2022-12-01
Journal:
Journal of Energy Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 13.1
ISSN: 20954956
Electrochemistry
Energy Engineering and Power Technology
Fuel Technology
Energy (miscellaneous)
Abstract
• Mismatch between PEO solid polymer electrolytes and 4.2 V-class cathodes is beyond the limited electrochemical window of PEO. • Interphasial degradation mechanism for high-voltage NMC cathode is identified at the solid PEO-NMC interface. • Oxidation of PEO initiates substantial interphasial reconstruction and special diffusion pathway of defects in solid batteries. • An effective LiF-containing protective layer on NMC can greatly improve the lifespan of NMC|PEO|Li batteries. Solid-state polymer electrolytes (SPEs) have attracted increasing attention due to good interfacial contact, light weight, and easy manufacturing. However, the practical application of SPEs such as the most widely studied poly(ethylene oxide) (PEO) in high-energy solid polymer batteries is still challenging, and the reasons are yet elusive. Here, it is found that the mismatch between PEO and 4.2 V-class cathodes is beyond the limited electrochemical window of PEO in the solid LiNi 1/3 Mn 1/3 Co 1/3 O 2 (NMC)-PEO batteries. The initial oxidation of PEO initiates remarkable surface reconstruction of NMC grains in solid batteries that is different from the situation in liquid electrolytes. Well-aligned nanovoids are observed in NMC grains during the diffusion of surface reconstruction layers towards the bulk in solid batteries. The substantial interphasial degradation, therefore, blocks smooth Li + transport across the NMC-PEO interface and causes performance degradation. A thin yet effective LiF-containing protection layer on NMC can effectively stabilize the NMC-PEO interface with a greatly improved lifespan of NMC|PEO|Li batteries. This work deepens the understanding of degradations in high-voltage solid-state polymer batteries.
Top-30
Citations by journals
|
1
2
|
|
|
Journal of Power Sources
2 publications, 15.38%
|
|
|
Journal of Energy Chemistry
2 publications, 15.38%
|
|
|
Materials Chemistry Frontiers
1 publication, 7.69%
|
|
|
Energy Storage Materials
1 publication, 7.69%
|
|
|
Chemical Science
1 publication, 7.69%
|
|
|
eTransportation
1 publication, 7.69%
|
|
|
Electrochimica Acta
1 publication, 7.69%
|
|
|
Advanced Energy and Sustainability Research
1 publication, 7.69%
|
|
|
Nano Energy
1 publication, 7.69%
|
|
|
Mechanical Systems and Signal Processing
1 publication, 7.69%
|
|
|
Russian Chemical Reviews
1 publication, 7.69%
|
|
|
1
2
|
Citations by publishers
|
1
2
3
4
5
6
7
8
9
|
|
|
Elsevier
9 publications, 69.23%
|
|
|
Royal Society of Chemistry (RSC)
2 publications, 15.38%
|
|
|
Wiley
1 publication, 7.69%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.69%
|
|
|
1
2
3
4
5
6
7
8
9
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[7,6],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["53.85","46.15"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Power Sources","Journal of Energy Chemistry","Materials Chemistry Frontiers","Energy Storage Materials","Chemical Science","eTransportation","Electrochimica Acta","Advanced Energy and Sustainability Research","Nano Energy","Mechanical Systems and Signal Processing","Russian Chemical Reviews"],"ids":[14844,20653,7063,3858,9646,25487,15613,27494,23236,25162,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[2,2,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[15.38,15.38,7.69,7.69,7.69,7.69,7.69,7.69,7.69,7.69,7.69],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Royal Society of Chemistry (RSC)","Wiley","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,123,11,9422],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[9,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[69.23,15.38,7.69,7.69],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0],"percentage":["0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0],"percentage":["0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0],"percentage":["0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[6,6],"percentage":["46.15","46.15"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0],"percentage":["7.69","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0],"percentage":["0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0],"percentage":["0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,0],"percentage":["7.69","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[5,6],"percentage":["38.46","46.15"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0],"percentage":["7.69","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex
Cite this
GOST
Copy
Huang R. et al. The interphasial degradation of 4.2 V-class poly(ethylene oxide)-based solid batteries beyond electrochemical voltage limit // Journal of Energy Chemistry. 2022. Vol. 75. pp. 504-511.
GOST all authors (up to 50)
Copy
Huang R., Yang D., Zhang F., Jiang W., Zhang C., Yan P., Ling M., Pan H. The interphasial degradation of 4.2 V-class poly(ethylene oxide)-based solid batteries beyond electrochemical voltage limit // Journal of Energy Chemistry. 2022. Vol. 75. pp. 504-511.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jechem.2022.06.014
UR - https://doi.org/10.1016/j.jechem.2022.06.014
TI - The interphasial degradation of 4.2 V-class poly(ethylene oxide)-based solid batteries beyond electrochemical voltage limit
T2 - Journal of Energy Chemistry
AU - Huang, Renzhi
AU - Yang, Da-Xin
AU - Zhang, Fenglin
AU - Jiang, Wei
AU - Zhang, Canfu
AU - Yan, Pengfei
AU - Ling, Min
AU - Pan, Huilin
PY - 2022
DA - 2022/12/01 00:00:00
PB - Elsevier
SP - 504-511
VL - 75
SN - 2095-4956
ER -
Cite this
BibTex
Copy
@article{2022_Huang,
author = {Renzhi Huang and Da-Xin Yang and Fenglin Zhang and Wei Jiang and Canfu Zhang and Pengfei Yan and Min Ling and Huilin Pan},
title = {The interphasial degradation of 4.2 V-class poly(ethylene oxide)-based solid batteries beyond electrochemical voltage limit},
journal = {Journal of Energy Chemistry},
year = {2022},
volume = {75},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/j.jechem.2022.06.014},
pages = {504--511},
doi = {10.1016/j.jechem.2022.06.014}
}
Profiles