Chemisorption interaction of liquid electrodes of gallium and In–Ga, Cd–Ga and Tl–Ga alloys with solvents in a wide range of their donor numbers
V. V. Emets
1
,
B. B. Damaskin
2
Publication type: Journal Article
Publication date: 2007-02-01
scimago Q1
wos Q1
SJR: 0.760
CiteScore: 8.1
Impact factor: 4.1
ISSN: 15726657, 18732569
General Chemical Engineering
Analytical Chemistry
Electrochemistry
Abstract
By the example of five liquid renewable electrodes of mercury, gallium, and In–Ga (16.4 at.% In), Cd–Ga (0.3 at.% Cd) and Tl–Ga (0.02 at.% Tl) alloys, the structure of electrical double layer (edl) on the sp-metals is studied in several solvents in a wide range of their donor numbers (from 14 to 55). In the solvents with high donor numbers (DN), namely, hexamethyl phosphortriamide (HMPTA, DN = 38.8) and ethylenediamine (EDA, DN = 55), very strong metal–solvent chemisorption interaction was recorded on the Ga, In–Ga, and Cd–Ga electrodes. The energy of chemisorption interaction of the metals with HMPTA and EDA increases in the sequence Hg
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Emets V. V., Damaskin B. B. Chemisorption interaction of liquid electrodes of gallium and In–Ga, Cd–Ga and Tl–Ga alloys with solvents in a wide range of their donor numbers // Journal of Electroanalytical Chemistry. 2007. Vol. 600. No. 1. pp. 191-204.
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Emets V. V., Damaskin B. B. Chemisorption interaction of liquid electrodes of gallium and In–Ga, Cd–Ga and Tl–Ga alloys with solvents in a wide range of their donor numbers // Journal of Electroanalytical Chemistry. 2007. Vol. 600. No. 1. pp. 191-204.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.jelechem.2006.07.008
UR - https://doi.org/10.1016/j.jelechem.2006.07.008
TI - Chemisorption interaction of liquid electrodes of gallium and In–Ga, Cd–Ga and Tl–Ga alloys with solvents in a wide range of their donor numbers
T2 - Journal of Electroanalytical Chemistry
AU - Emets, V. V.
AU - Damaskin, B. B.
PY - 2007
DA - 2007/02/01
PB - Elsevier
SP - 191-204
IS - 1
VL - 600
SN - 1572-6657
SN - 1873-2569
ER -
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BibTex (up to 50 authors)
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@article{2007_Emets,
author = {V. V. Emets and B. B. Damaskin},
title = {Chemisorption interaction of liquid electrodes of gallium and In–Ga, Cd–Ga and Tl–Ga alloys with solvents in a wide range of their donor numbers},
journal = {Journal of Electroanalytical Chemistry},
year = {2007},
volume = {600},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.jelechem.2006.07.008},
number = {1},
pages = {191--204},
doi = {10.1016/j.jelechem.2006.07.008}
}
Cite this
MLA
Copy
Emets, V. V., and B. B. Damaskin. “Chemisorption interaction of liquid electrodes of gallium and In–Ga, Cd–Ga and Tl–Ga alloys with solvents in a wide range of their donor numbers.” Journal of Electroanalytical Chemistry, vol. 600, no. 1, Feb. 2007, pp. 191-204. https://doi.org/10.1016/j.jelechem.2006.07.008.