volume 816 pages 21-29

Potentiometric sensors arrays based on perfluorinated membranes and silica nanoparticles with surface modified by proton-acceptor groups, for the determination of aspartic and glutamic amino acids anions and potassium cations

Publication typeJournal Article
Publication date2018-05-01
scimago Q1
wos Q1
SJR0.760
CiteScore8.1
Impact factor4.1
ISSN15726657, 18732569
General Chemical Engineering
Analytical Chemistry
Electrochemistry
Abstract
Hybrid materials based on perfluorosulfonic cation-exchange membranes and silica nanoparticles with surface modified by nitrogen-containing groups have been obtained. The influence of concentration, size and proton acceptor ability of modifying groups on the oxide surface onto the response stability and sensitivity of potentiomentric sensors in aspartic and glutamic acid solutions with pH 4–9 has been investigated. A correlation between sensor cross-sensitivity to cations and anions in test solutions and membrane diffusion permeability is revealed. Optimal membrane compositions for arrays of cross-sensitive sensors have been chosen. Proposed sensors allow to carry out a simultaneous determination of potassium cations and amino acid anions in test solutions with concentrations ranged from 1.0·10 −4 to 1.0·10 −2  M, with an error
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Safronova E. et al. Potentiometric sensors arrays based on perfluorinated membranes and silica nanoparticles with surface modified by proton-acceptor groups, for the determination of aspartic and glutamic amino acids anions and potassium cations // Journal of Electroanalytical Chemistry. 2018. Vol. 816. pp. 21-29.
GOST all authors (up to 50) Copy
Safronova E., Parshina A., Kоlganova T., Bobreshova O., Pourcelly G., Yaroslavtsev A. B. Potentiometric sensors arrays based on perfluorinated membranes and silica nanoparticles with surface modified by proton-acceptor groups, for the determination of aspartic and glutamic amino acids anions and potassium cations // Journal of Electroanalytical Chemistry. 2018. Vol. 816. pp. 21-29.
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TY - JOUR
DO - 10.1016/j.jelechem.2018.03.028
UR - https://linkinghub.elsevier.com/retrieve/pii/S1572665718301978
TI - Potentiometric sensors arrays based on perfluorinated membranes and silica nanoparticles with surface modified by proton-acceptor groups, for the determination of aspartic and glutamic amino acids anions and potassium cations
T2 - Journal of Electroanalytical Chemistry
AU - Safronova, Ekaterina
AU - Parshina, Anna
AU - Kоlganova, Tatyana
AU - Bobreshova, Olga
AU - Pourcelly, Gérald
AU - Yaroslavtsev, A. B.
PY - 2018
DA - 2018/05/01
PB - Elsevier
SP - 21-29
VL - 816
SN - 1572-6657
SN - 1873-2569
ER -
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BibTex (up to 50 authors) Copy
@article{2018_Safronova,
author = {Ekaterina Safronova and Anna Parshina and Tatyana Kоlganova and Olga Bobreshova and Gérald Pourcelly and A. B. Yaroslavtsev},
title = {Potentiometric sensors arrays based on perfluorinated membranes and silica nanoparticles with surface modified by proton-acceptor groups, for the determination of aspartic and glutamic amino acids anions and potassium cations},
journal = {Journal of Electroanalytical Chemistry},
year = {2018},
volume = {816},
publisher = {Elsevier},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1572665718301978},
pages = {21--29},
doi = {10.1016/j.jelechem.2018.03.028}
}