Journal of Electroanalytical Chemistry, volume 881, pages 114916

Atomic-scale Al2O3 modified PEO-based composite polymer electrolyte for durable solid-state Li − S batteries

Yuanyuan Shi ¹

Zengjie Fan ¹

Bing Ding ¹

Zhiwei Li ¹

Qingyang Lin ¹

Shuang Chen ¹

Hui Dou ¹

Xiaogang Zhang ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Jiangsu Key Laboratory of Electrochemical Energy Storage Technologies, College of Material Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, PR China |

Publication type: Journal Article

Publication date: 2021-01-01

Elsevier

Journal: Journal of Electroanalytical Chemistry

Quartile SCImago

Quartile WOS

Impact factor: 4.5

ISSN: 15726657

DOI: 10.1016/j.jelechem.2020.114916

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General Chemical Engineering

Analytical Chemistry

Electrochemistry

Abstract

The dissolution of lithium polysulfides in the polymer-based electrolyte and the electrolyte/lithium interface instability lead to the poor cycling stability and low Coulombic efficiency of solid-state Li S batteries. Herein, an ultrathin Al2O3 layer is deposited on the polyethylene oxide (PEO) based composite polymer electrolyte (CPE) by atomic layer deposition (ALD) to build a stable electrolyte/lithium interface, which could inhibit the shuttle effect of lithium polysulfides and restrain the growth of Li dendrite. An ultralong life in Li Li symmetric cell with CPE/Al2O3 can be achieved over 1200 h. The solid-state Li S batteries with the flexible CPE/Al2O3 membrane also deliver the electrochemical performance with high initial capacity of 1415 mAh g−1 and a reversible capacity of 640 mAh g−1 after 120 cycles at 0.1C. In addition, the fabricated punch cell with CPE/Al2O3 can endure the harsh treatment and operate at least 50 cycles, showing great potential in practical application.

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Citations by journals

	1 2 3
Materials Today Energy	Materials Today Energy, 3, 6% Materials Today Energy 3 publications, 6%
Advanced Energy Materials	Advanced Energy Materials, 3, 6% Advanced Energy Materials 3 publications, 6%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 3, 6% Journal of Materials Chemistry A 3 publications, 6%
Nanoscale	Nanoscale, 3, 6% Nanoscale 3 publications, 6%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 2, 4% Journal of Colloid and Interface Science 2 publications, 4%
Journal of Electroanalytical Chemistry	Journal of Electroanalytical Chemistry, 2, 4% Journal of Electroanalytical Chemistry 2 publications, 4%
Journal of Energy Chemistry	Journal of Energy Chemistry, 2, 4% Journal of Energy Chemistry 2 publications, 4%
Advanced Functional Materials	Advanced Functional Materials, 2, 4% Advanced Functional Materials 2 publications, 4%
Advanced Materials	Advanced Materials, 2, 4% Advanced Materials 2 publications, 4%
Nano-Micro Letters	Nano-Micro Letters, 1, 2% Nano-Micro Letters 1 publication, 2%
Small	Small, 1, 2% Small 1 publication, 2%
Journal of Power Sources	Journal of Power Sources, 1, 2% Journal of Power Sources 1 publication, 2%
Matter	Matter, 1, 2% Matter 1 publication, 2%
Ceramics International	Ceramics International, 1, 2% Ceramics International 1 publication, 2%
Sustainable Materials and Technologies	Sustainable Materials and Technologies, 1, 2% Sustainable Materials and Technologies 1 publication, 2%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2% ACS Applied Energy Materials 1 publication, 2%
Journal of the Taiwan Institute of Chemical Engineers	Journal of the Taiwan Institute of Chemical Engineers, 1, 2% Journal of the Taiwan Institute of Chemical Engineers 1 publication, 2%
Battery Energy	Battery Energy, 1, 2% Battery Energy 1 publication, 2%
ACS Omega	ACS Omega, 1, 2% ACS Omega 1 publication, 2%
ACS Nano	ACS Nano, 1, 2% ACS Nano 1 publication, 2%
RSC Advances	RSC Advances, 1, 2% RSC Advances 1 publication, 2%
eTransportation	eTransportation, 1, 2% eTransportation 1 publication, 2%
Electrochimica Acta	Electrochimica Acta, 1, 2% Electrochimica Acta 1 publication, 2%
Journal of Energy Storage	Journal of Energy Storage, 1, 2% Journal of Energy Storage 1 publication, 2%
Next Nanotechnology	Next Nanotechnology, 1, 2% Next Nanotechnology 1 publication, 2%
Electron	Electron, 1, 2% Electron 1 publication, 2%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 2% Journal of Alloys and Compounds 1 publication, 2%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 2% ACS applied materials & interfaces 1 publication, 2%
ACS Applied Nano Materials	ACS Applied Nano Materials, 1, 2% ACS Applied Nano Materials 1 publication, 2%
	1 2 3

Citations by publishers

	5 10 15 20 25
Elsevier	Elsevier, 21, 42% Elsevier 21 publications, 42%
Wiley	Wiley, 10, 20% Wiley 10 publications, 20%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 8, 16% Royal Society of Chemistry (RSC) 8 publications, 16%
American Chemical Society (ACS)	American Chemical Society (ACS), 5, 10% American Chemical Society (ACS) 5 publications, 10%
Springer Nature	Springer Nature, 2, 4% Springer Nature 2 publications, 4%
Taiwan Institute of Chemical Engineers	Taiwan Institute of Chemical Engineers, 1, 2% Taiwan Institute of Chemical Engineers 1 publication, 2%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 1, 2% American Association for the Advancement of Science (AAAS) 1 publication, 2%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 2% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 2%
	5 10 15 20 25

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Shi Y. et al. Atomic-scale Al2O3 modified PEO-based composite polymer electrolyte for durable solid-state Li − S batteries // Journal of Electroanalytical Chemistry. 2021. Vol. 881. p. 114916.

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Shi Y., Fan Z., Ding B., Li Z., Lin Q., Chen S., Dou H., Zhang X. Atomic-scale Al2O3 modified PEO-based composite polymer electrolyte for durable solid-state Li − S batteries // Journal of Electroanalytical Chemistry. 2021. Vol. 881. p. 114916.

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RIS Copy

TY - JOUR

DO - 10.1016/j.jelechem.2020.114916

UR - https://doi.org/10.1016/j.jelechem.2020.114916

TI - Atomic-scale Al2O3 modified PEO-based composite polymer electrolyte for durable solid-state Li − S batteries

T2 - Journal of Electroanalytical Chemistry

AU - Shi, Yuanyuan

AU - Fan, Zengjie

AU - Ding, Bing

AU - Li, Zhiwei

AU - Lin, Qingyang

AU - Chen, Shuang

AU - Dou, Hui

AU - Zhang, Xiaogang

PY - 2021

DA - 2021/01/01 00:00:00

PB - Elsevier

SP - 114916

VL - 881

SN - 1572-6657

ER -

BibTex

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BibTex Copy

@article{2021_Shi,

author = {Yuanyuan Shi and Zengjie Fan and Bing Ding and Zhiwei Li and Qingyang Lin and Shuang Chen and Hui Dou and Xiaogang Zhang},

title = {Atomic-scale Al2O3 modified PEO-based composite polymer electrolyte for durable solid-state Li − S batteries},

journal = {Journal of Electroanalytical Chemistry},

year = {2021},

volume = {881},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/j.jelechem.2020.114916},

pages = {114916},

doi = {10.1016/j.jelechem.2020.114916}

}

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Publisher

Elsevier

Journal

Journal of Electroanalytical Chemistry

Quartile SCImago

Quartile WOS

Impact factor

4.5

ISSN

15726657 (Print)