volume 31 issue 13 pages 2377-2385

Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties

Gendre Mathieu 1
Alexandre Maître 1
Gilles Trolliard 1
1
 
Laboratoire Science des Procédés Céramiques et Traitements de Surface, UMR CNRS 6638, Centre Européen de la Céramique, 12, rue Atlantis, 87068 Limoges Cedex, France
Publication typeJournal Article
Publication date2011-11-01
scimago Q1
wos Q1
SJR1.300
CiteScore11.5
Impact factor6.2
ISSN09552219, 1873619X
Materials Chemistry
Ceramics and Composites
Abstract
Different stoichiometries of zirconium oxycarbide (ZrCxOy) powders were synthesised by carboreduction to approach the role of the chemical composition on the densification behaviour during spark plasma sintering and on the mechanical properties. Chemical analyses were performed using complementary methods to determine the actual stoichiometry and homogeneity of powders. Evolution of relative density during SPS treatment and microstructure observations by SEM showed that oxygen and vacancy contents would enhance the densification kinetics by promoting the lattice diffusion of limiting species. A study of mechanical properties of SPS sintered specimens has highlighted their significant dependence on the oxycarbide stoichiometry, especially at high temperature.
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GOST |
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GOST Copy
Mathieu G. et al. Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties // Journal of the European Ceramic Society. 2011. Vol. 31. No. 13. pp. 2377-2385.
GOST all authors (up to 50) Copy
Mathieu G., Maître A., Trolliard G. Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties // Journal of the European Ceramic Society. 2011. Vol. 31. No. 13. pp. 2377-2385.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.jeurceramsoc.2011.05.037
UR - https://doi.org/10.1016/j.jeurceramsoc.2011.05.037
TI - Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties
T2 - Journal of the European Ceramic Society
AU - Mathieu, Gendre
AU - Maître, Alexandre
AU - Trolliard, Gilles
PY - 2011
DA - 2011/11/01
PB - Elsevier
SP - 2377-2385
IS - 13
VL - 31
SN - 0955-2219
SN - 1873-619X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Mathieu,
author = {Gendre Mathieu and Alexandre Maître and Gilles Trolliard},
title = {Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties},
journal = {Journal of the European Ceramic Society},
year = {2011},
volume = {31},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.jeurceramsoc.2011.05.037},
number = {13},
pages = {2377--2385},
doi = {10.1016/j.jeurceramsoc.2011.05.037}
}
MLA
Cite this
MLA Copy
Mathieu, Gendre, et al. “Synthesis of zirconium oxycarbide (ZrCxOy) powders: Influence of stoichiometry on densification kinetics during spark plasma sintering and on mechanical properties.” Journal of the European Ceramic Society, vol. 31, no. 13, Nov. 2011, pp. 2377-2385. https://doi.org/10.1016/j.jeurceramsoc.2011.05.037.