Journal of the European Ceramic Society, volume 38, issue 4, pages 1673-1678
Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site
Jianli Gai
1
,
Erqing Zhao
2
,
Furui Ma
1
,
Deye Sun
1
,
Xiaodi Ma
1
,
Yongcheng Jin
1
,
Qingliu Wu
3
,
Yongjie Cui
4
1
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese of Academy of Sciences, 189 Songling Road, Qindao, 266101, China
|
Publication type: Journal Article
Publication date: 2018-04-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 09552219, 1873619X
Materials Chemistry
Ceramics and Composites
Abstract
The elements Nb and Y were simultaneously substituted to the Zr sites of an Li7La3Zr2O12 (LLZO) electrolyte to improve its Li-ion conductivity and air stability. Samples of Li7La3Zr2-2xNbxYxO12 were fabricated using a solid-state reaction method. The results show that the introduction of Nb and Y can stabilise cubic-phase LLZO. The total conductivity of Li7La3ZrNb0.5Y0.5O12 electrolyte can reach 8.29 × 10−4 S cm−1 at 30 °C when sintered at 1230 °C for only 15 h. Surprisingly, the conductivity of Li7La3ZrNb0.5Y0.5O12 can be maintained at 6.91 × 10−4 S cm−1 after exposure to air for 1.5 months, indicating excellent air stability. Furthermore, a LiFePO4/Li7La3ZrNb0.5Y0.5O12/Li cell displayed stable charge/discharge and cycling performance at ambient temperature, suggesting there is potential to use Li7La3ZrNb0.5Y0.5O12 electrolyte in Li-ion batteries. Additionally, the effects of varying the co-doping amount and dwelling time on the Li-ion conductivity of Li7La3Zr2-2xNbxYxO12 were investigated.
Top-30
Citations by journals
|
1
2
3
4
5
6
7
|
|
|
Journal of Power Sources
7 publications, 6.67%
|
|
|
Journal of the European Ceramic Society
5 publications, 4.76%
|
|
|
Solid State Ionics
5 publications, 4.76%
|
|
|
Journal of Materials Chemistry A
5 publications, 4.76%
|
|
|
Ionics
4 publications, 3.81%
|
|
|
Energy Storage Materials
4 publications, 3.81%
|
|
|
Ceramics International
4 publications, 3.81%
|
|
|
Advanced Energy Materials
4 publications, 3.81%
|
|
|
ACS applied materials & interfaces
3 publications, 2.86%
|
|
|
Journal of the Electrochemical Society
2 publications, 1.9%
|
|
|
Journal of the American Ceramic Society
2 publications, 1.9%
|
|
|
Applied Physics A: Materials Science and Processing
2 publications, 1.9%
|
|
|
Rare Metals
2 publications, 1.9%
|
|
|
Journal of Alloys and Compounds
2 publications, 1.9%
|
|
|
Journal of Energy Storage
2 publications, 1.9%
|
|
|
AIP Conference Proceedings
2 publications, 1.9%
|
|
|
Canadian Journal of Chemistry
1 publication, 0.95%
|
|
|
Micromachines
1 publication, 0.95%
|
|
|
Electrochem
1 publication, 0.95%
|
|
|
Energies
1 publication, 0.95%
|
|
|
Bulletin of Materials Science
1 publication, 0.95%
|
|
|
Journal of Advanced Ceramics
1 publication, 0.95%
|
|
|
International Journal of Minerals, Metallurgy and Materials
1 publication, 0.95%
|
|
|
Journal of Materials Science: Materials in Electronics
1 publication, 0.95%
|
|
|
Electrochemical Energy Reviews
1 publication, 0.95%
|
|
|
Materials Chemistry and Physics
1 publication, 0.95%
|
|
|
Chemical Engineering Journal
1 publication, 0.95%
|
|
|
Physica B: Condensed Matter
1 publication, 0.95%
|
|
|
IOP Conference Series: Earth and Environmental Science
1 publication, 0.95%
|
|
|
1
2
3
4
5
6
7
|
Citations by publishers
|
5
10
15
20
25
30
35
40
45
|
|
|
Elsevier
43 publications, 40.95%
|
|
|
Royal Society of Chemistry (RSC)
12 publications, 11.43%
|
|
|
Wiley
10 publications, 9.52%
|
|
|
Springer Nature
10 publications, 9.52%
|
|
|
American Chemical Society (ACS)
8 publications, 7.62%
|
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
4 publications, 3.81%
|
|
|
American Institute of Physics (AIP)
3 publications, 2.86%
|
|
|
The Electrochemical Society
2 publications, 1.9%
|
|
|
Nonferrous Metals Society of China
2 publications, 1.9%
|
|
|
IOP Publishing
2 publications, 1.9%
|
|
|
Canadian Science Publishing
1 publication, 0.95%
|
|
|
Tsinghua University Press
1 publication, 0.95%
|
|
|
University of Science and Technology Beijing
1 publication, 0.95%
|
|
|
Institute of Research and Community Services Diponegoro University (LPPM UNDIP)
1 publication, 0.95%
|
|
|
Korean Ceramic Society
1 publication, 0.95%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.95%
|
|
|
5
10
15
20
25
30
35
40
45
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0],"imageUrls":["","","","","","",""],"datasets":[{"label":"Citations number","data":[2,15,15,24,18,16,15],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["1.9","14.29","14.29","22.86","17.14","15.24","14.29"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Power Sources","Journal of the European Ceramic Society","Solid State Ionics","Journal of Materials Chemistry A","Ionics","Energy Storage Materials","Ceramics International","Advanced Energy Materials","ACS applied materials & interfaces","Journal of the Electrochemical Society","Journal of the American Ceramic Society","Applied Physics A: Materials Science and Processing","Rare Metals","Journal of Alloys and Compounds","Journal of Energy Storage","AIP Conference Proceedings","Canadian Journal of Chemistry","Micromachines","Electrochem","Energies","Bulletin of Materials Science","Journal of Advanced Ceramics","International Journal of Minerals, Metallurgy and Materials","Journal of Materials Science: Materials in Electronics","Electrochemical Energy Reviews","Materials Chemistry and Physics","Chemical Engineering Journal","Physica B: Condensed Matter","IOP Conference Series: Earth and Environmental Science"],"ids":[14844,9459,12542,14919,12191,3858,15103,22475,1458,5297,24329,14766,18829,4015,18623,21274,21147,1083,27757,23828,20207,5243,6632,20208,25884,12041,16275,18171,6042],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/qZfu8vVyaDIo81Au73p6SNE8AGGzf73yfiTC33bu_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/ZBf59wI1SMgSL89rU8cJXRfzrfAz8slfIClYmcuk_medium.webp","","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp"],"datasets":[{"label":"","data":[7,5,5,5,4,4,4,4,3,2,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[6.67,4.76,4.76,4.76,3.81,3.81,3.81,3.81,2.86,1.9,1.9,1.9,1.9,1.9,1.9,1.9,0.95,0.95,0.95,0.95,0.95,0.95,0.95,0.95,0.95,0.95,0.95,0.95,0.95],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Royal Society of Chemistry (RSC)","Wiley","Springer Nature","American Chemical Society (ACS)","Multidisciplinary Digital Publishing Institute (MDPI)","American Institute of Physics (AIP)","The Electrochemical Society","Nonferrous Metals Society of China","IOP Publishing","Canadian Science Publishing","Tsinghua University Press","University of Science and Technology Beijing","Institute of Research and Community Services Diponegoro University (LPPM UNDIP)","Korean Ceramic Society","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,123,11,8,40,202,250,6916,1585,2075,6942,1836,2262,7725,1949,9422],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/ARM4e6URKRsbRZvIF0vFis9DjxGloBjnBYJXbHmZ_medium.webp","\/storage\/images\/resized\/s6nfxitVCZUsdJiJZESaAXqdmMJxom8q4Ps6ayL2_medium.webp","","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/qZfu8vVyaDIo81Au73p6SNE8AGGzf73yfiTC33bu_medium.webp","\/storage\/images\/resized\/ZBf59wI1SMgSL89rU8cJXRfzrfAz8slfIClYmcuk_medium.webp","","","","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[43,12,10,10,8,4,3,2,2,2,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[40.95,11.43,9.52,9.52,7.62,3.81,2.86,1.9,1.9,1.9,0.95,0.95,0.95,0.95,0.95,0.95],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,1,1,0,1],"percentage":["0","0","0","0.95","0.95","0","0.95"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,3,5,5,1,2,0],"percentage":["0.95","2.86","4.76","4.76","0.95","1.9","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,9,10,15,14,12,14],"percentage":["0.95","8.57","9.52","14.29","13.33","11.43","13.33"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,3,0,3,2,2,0],"percentage":["0","2.86","0","2.86","1.9","1.9","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,1,1,0,0],"percentage":["0","0","0","0.95","0.95","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1,0,1,0,1],"percentage":["0","0","0.95","0","0.95","0","0.95"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,2,6,5,3,2,0],"percentage":["0.95","1.9","5.71","4.76","2.86","1.9","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,10,8,14,11,12,14],"percentage":["0.95","9.52","7.62","13.33","10.48","11.43","13.33"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,3,0,4,2,2,0],"percentage":["0","2.86","0","3.81","1.9","1.9","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Gai J. et al. Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site // Journal of the European Ceramic Society. 2018. Vol. 38. No. 4. pp. 1673-1678.
GOST all authors (up to 50)
Copy
Gai J., Zhao E., Ma F., Sun D., Ma X., Jin Y., Wu Q., Cui Y. Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site // Journal of the European Ceramic Society. 2018. Vol. 38. No. 4. pp. 1673-1678.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jeurceramsoc.2017.12.002
UR - https://doi.org/10.1016/j.jeurceramsoc.2017.12.002
TI - Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site
T2 - Journal of the European Ceramic Society
AU - Gai, Jianli
AU - Zhao, Erqing
AU - Ma, Furui
AU - Sun, Deye
AU - Ma, Xiaodi
AU - Jin, Yongcheng
AU - Wu, Qingliu
AU - Cui, Yongjie
PY - 2018
DA - 2018/04/01 00:00:00
PB - Elsevier
SP - 1673-1678
IS - 4
VL - 38
SN - 0955-2219
SN - 1873-619X
ER -
Cite this
BibTex
Copy
@article{2018_Gai,
author = {Jianli Gai and Erqing Zhao and Furui Ma and Deye Sun and Xiaodi Ma and Yongcheng Jin and Qingliu Wu and Yongjie Cui},
title = {Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site},
journal = {Journal of the European Ceramic Society},
year = {2018},
volume = {38},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.jeurceramsoc.2017.12.002},
number = {4},
pages = {1673--1678},
doi = {10.1016/j.jeurceramsoc.2017.12.002}
}
Cite this
MLA
Copy
Gai, Jianli, et al. “Improving the Li-ion conductivity and air stability of cubic Li7La3Zr2O12 by the co-doping of Nb, Y on the Zr site.” Journal of the European Ceramic Society, vol. 38, no. 4, Apr. 2018, pp. 1673-1678. https://doi.org/10.1016/j.jeurceramsoc.2017.12.002.